The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The appearance of this amalgam is so
very like that of the ammoniacal compound formed by exposing a
solution of ammonia in contact with mercury to the influence of
the Voltaic pile, or when an amalgam of potassium and mercury is
placed upon moistened muriate of ammonia, that it is impossible
not to be struck with the resemblance. Mr. Daniell is therefore
inclined to believe that the production of the latter may be
explained upon the same principles as that of the former.
When the effect is produced by the direct application of the
electrical current, by means of the battery, it ceases the moment
the connexion between the poles is broken; and when brought about
by the agency of the amalgam of potassium, the electrical action
is doubtless excited by the contact of the two dissimilar metals,
and the frothy compound lasts no longer than the existence of the
potassium in the metallic state; whereas in the action between
mercury and finely divided platinum, the permanence of the metals
produces a much more lasting effect, and the soft amalgam may
therefore be preserved for a greater length of time.
Mr. Brande, in a late communication in the Journal of the Royal
Institution,[85] observes: "Shortly after the discovery of a method
of obtaining Morphia in a pure state, I remember that Sir Humphry
Davy suggested the possibility of its affording, when electrised
in contact with mercury, results corresponding with those which
Berzelius had observed in respect to ammonia. He thought that
the nascent elements of the morphia, as liberated by electrical
decomposition, might, under such circumstances, effect a similar
apparent amalgam of the mercury, and he spoke of the subject as
likely to throw some light upon the corresponding ammoniacal
combinations. He made, I believe, a few experiments upon the
subject; but as the results were not such as he had anticipated,
they were not placed on record."
[85] "On the Electro-chemical Decomposition of the
Vegeto-Alkaline Salts." In this communication, the Professor
gives an account of some experiments of his own, with a view
to ascertain whether the vegetable alkalies, if electrised in
contact with mercury, would impart any principle to the latter
metal. In experiments with morphia and cinchonia, in which the
mercury in contact with the vegetable base was rendered negative,
not the least change in the fluidity of the metal could be
perceived. When, however, a similar experiment was made with
quina, the metal became filmy, and acquired even a tendency to a
butyraceous appearance, but the phenomenon was found to depend
upon the presence of a minute portion of lime.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account