The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The enquiry commences with experiments on the results produced
by the mutual action of potassium and ammonia on each other. His
object was twofold: to refute the hypothesis which assumed hydrogen
as an element of potassium, and to ascertain the nature of the
matter existing in the amalgam of ammonia, or the supposed metallic
basis of the volatile alkali: a question intimately connected with
the whole of the arrangements of chemistry. As to the former point,
it is unnecessary to enter into farther discussion; and with regard
to the latter, it is quite impossible to convey an adequate idea of
the extent of the enquiry: there does not exist in the annals of
chemistry a more striking example of experimental industry.
In the course of his experiments on potassium and ammonia, he
obtained an olive-coloured body, which he was inclined to regard
as a compound of the metallic base of ammonia (_ammonium_) and
potassium; and on submitting which to various trials, he uniformly
obtained, as the product of its decomposition, a proportion of
nitrogen considerably less than that which, upon calculations
founded on a rigid analysis of the volatile alkali, ought to
have been afforded under such circumstances, while the potassium
employed at the same time became oxidated. This result inspired a
hope that nitrogen might have been actually decomposed during the
process, and that its elements were oxygen and a metallic basis, or
oxygen and hydrogen.
That he was sanguine in that hope, appears from the whole tenor
of his paper; in farther proof of which, I can adduce a letter
which he addressed to Mr. Children during the progress of his
experiments, in which he says, "I hope on Thursday to show you
nitrogen as a complete wreck, torn to pieces in different ways."
His subsequent enquiries, however, although they did not strengthen
the suspicion he had formed respecting the decomposition of that
body, yet indirectly developed facts of considerable importance;
which, with his characteristic quickness of perception, he made
subservient to fresh investigation.
His researches into the phenomena exhibited by tellurium, when
forming a part of the Voltaic circuit, are highly interesting. It
had been stated by Ritter, that, of all the metallic substances he
tried for producing potassium by negative electricity, tellurium
was the only one by which he could not procure it; and he uses this
fact in support of his opinion, that potassium is a _hydruret_.
He says, that when a circuit of electricity is completed in water
by means of two surfaces of tellurium, oxygen is given off at the
positive surface, and instead of hydrogen at the negative surface,
a brown powder is formed and separated, which he regards as a
_hydruret_ of tellurium; and he conceives that the reason why
that metal prevents the metallization of potash is, that it has a
stronger attraction for hydrogen than that possessed by the alkali.
Public-domain text, read in full here on John Shaqi.
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