The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Davy's attention was naturally arrested by such a statement,
and, in pursuing the enquiry, he discovered a series of new
facts:--he found that tellurium and hydrogen were capable of
combining, and of forming a gas, to which he gave the name of
_telluretted hydrogen_,--that, so far from tellurium preventing the
decomposition of potash, it formed an alloy with potassium when
negatively electrified upon the alkali--and, such was the intense
affinity of potassium and tellurium for each other, that the
decomposition of potash might be effected by acting on the oxide
of the latter metal and the alkali, at the same time, by heated
charcoal.
With respect to the next subject of enquiry in these papers,
_viz._ whether sulphur, phosphorus, and carbon, in their ordinary
forms, may not contain hydrogen, it would appear that from an
experiment performed by Mr. Clayfield, and which Davy witnessed
at Bristol in the year 1799, he was very early led to suspect the
existence of hydrogen in sulphur; but it was not until 1807, that
he entered upon the investigation of the subject. From the general
tenor of his experiments he concluded that, in its common state,
it may be regarded as a compound, of small quantities of oxygen
and hydrogen, with a large quantity of a basis which, on account
of its strong attractions for other bodies, has not hitherto been
obtained in its pure form. The same analogies apply to phosphorus
and carbon. His conclusion was mainly derived from the fact,
that hydrogen is produced from sulphur and phosphorus in such
quantities by Voltaic electricity, that he thinks it cannot well be
considered as an accidental ingredient in them: the presence of
oxygen, he contends, may be inferred from the circumstance that,
when potassium is made to act upon these bodies, the sulphurets
and phosphurets so formed evolve by the action of an acid less
hydrogen, in the form of compound inflammable gas, than the same
quantity of potassium in an uncombined state. The question,
however, still remains in considerable doubt; and in his "Elements
of Chemical Philosophy," published four years afterwards, he admits
that no accurate conclusions have been formed on the subject.
In his second Bakerian Lecture of 1807, Davy had given an account
of an experiment in which boracic acid appeared to be decomposed
by Voltaic electricity, a dark-coloured inflammable substance
separating from it on the negative surface. In the memoir now
under consideration, he procured the basis by heating together
boracic acid and potassium, when he ascertained it to be a peculiar
inflammable matter, which, after various experiments upon its
nature, he was inclined to regard as metallic; on which account he
proposed for it the name of _Boracium_. At about the same period,
MM. Gay Lussac and Thénard were engaged in investigating the same
subject in France, and they anticipated him in some of the results.
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