The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The body of evidence by which Davy overthrew this doctrine, and
established the undecompounded nature of oxymuriatic acid, is to
be found in a succession of papers read before the Royal Society,
_viz._ in that already announced,--in his Bakerian Lecture for
1810,--and in a subsequent memoir read in February 1811.
It will be impossible for me to follow the author through all the
intricacies of the enquiry; but I shall seize upon some of its more
prominent points, and give a general outline of its bearings.
No sooner had his suspicions been excited with regard to the
compound nature of oxymuriatic acid, than it occurred to him that,
if oxygen were really present in that body, he might readily obtain
it from some of its compounds; that, for instance, its combination
with tin would yield an oxide of that metal by ammonia; while
those with phosphorus would furnish, on analysis, either the
phosphor_ous_, or phosphor_ic_ acid. But after experiments in which
the presence of water was most cautiously excluded, the results he
had anticipated were not obtained. In the place of an oxide of tin,
the product, on the application of heat, volatilized in dense and
pungent fumes; and, instead of obtaining an acid of phosphorus, a
body possessing new and unexpected properties resulted. Again,--it
had been stated, in confirmation of the theory that recognised the
presence of oxygen in oxymuriatic acid, that when this latter body
and ammonia were made to act upon each other, water was formed: our
chemist frequently repeated the experiment, and convinced himself
that such was not the fact.
It had been shown by Mr. Cruickshank, and more recently proved by
MM. Gay Lussac and Thénard, that oxymuriatic acid and hydrogen,
when mixed in nearly equal proportions, produce a matter almost
entirely condensable by water, which is common muriatic acid;
and that water is not deposited in the operation. Davy made many
experiments on the subject, and he found, that when these gases
were mingled together in equal volumes over water, introduced into
an exhausted vessel, and fired by the electric spark, muriatic acid
resulted, although, at the same time, there was a certain degree of
condensation, and a slight deposition of vapour; but on repeating
the experiment in a manner still more refined, and by carefully
drying the gases, such condensation became proportionally less.
When, in addition to the above experimental evidence, it is stated
that MM. Gay Lussac and Thénard had proved, by a copious collection
of instances, that in the usual cases where oxygen is eliminated
from oxymuriatic acid, water is always present, and muriatic acid
gas is formed; and as it has been moreover shown that oxymuriatic
is converted into muriatic acid gas by combining with hydrogen, it
is scarcely possible to avoid the conclusion, that the oxygen is
derived from the decomposition of water, and not from that of the
acid.
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