The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
When mercury is made to act, by means of Voltaic electricity, upon
one volume of muriatic acid gas, all the acid disappears, calomel
is formed, and half a volume of hydrogen is evolved.
By such experiments and arguments, Davy was led to the conclusion
that, as yet, oxymuriatic acid has not been decompounded; that it
is a peculiar body, elementary as far as our knowledge extends, and
analogous, in its tendency of combination with inflammable matter,
to oxygen gas; that, in fact, it may be a _peculiar_ acidifying and
dissolving principle, forming with different substances compounds
analogous to acids containing oxygen, or to oxides, in their
properties and powers of combination, but differing from them in
being, for the most part, decomposable by water. On this idea, he
thinks that muriatic acid may be considered as having hydrogen for
its base, and oxymuriatic acid for its acidifying principle. In
confirmation of such an opinion, it is also important to remark,
that in its electrical relations, oxymuriatic acid maintains its
analogy to oxygen.
The vivid combustion of bodies in oxymuriatic acid gas, Davy
acknowledges, may, at first view, appear a reason why oxygen should
be admitted as one of its elements; but he answers this argument
by stating, that heat and light are merely results of the intense
agency of combination; and that sulphur and metals, alkaline earths
and acids, become alike ignited under such circumstances.
As change of theory with regard to the primitive must necessarily
modify all our views with respect to the nature of secondary
bodies, so must this new view of oxymuriatic acid affect all our
opinions respecting its compounds. Davy accordingly proceeded, in
the first place, to investigate the various bodies which had been
distinguished by the name of _hyper-oxymuriates_, _muriates_, &c.
It also became necessary to alter the nomenclature, since to call
a body which neither contains oxygen nor muriatic acid, by a term
which denotes the presence of both, is contrary to those very
principles which first suggested it. Having consulted some of the
most eminent philosophers, Davy proposed a name founded upon one of
the most obvious and characteristic properties of the oxymuriatic
acid, namely, its colour, and called it CHLORINE.
If then oxymuriatic acid, or chlorine, does not contain any oxygen,
a question immediately arises as to the true nature of those
compounds in which the muriatic acid has been supposed to exist in
combination with a much larger proportion of oxygen than in the
oxymuriatic acid,--in the state in which it has been named by Mr.
Chenevix _hyper-oxygenized_ muriatic acid.
Public-domain text, read in full here on John Shaqi.
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