The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
[89] Experience has not confirmed the value of this suggestion.
Davy imagined that the vegetable fibre was injured by the
saline residuum; and having found that muriate of magnesia was
less corrosive than muriate of lime, he was led to propose
the substitute above stated. The fact, however, is, that the
fibre is injured by the chlorine; and as this body has only a
slight affinity for magnesia, it too quickly abandons it; and
consequently the oxymuriate of lime is still preferred.
It has been very truly observed, that all knowledge which is gained
tends towards the acquisition of more, just as the iron dug from
the mine facilitates in return the working of the miner. Never
was this truth more forcibly illustrated than by the discovery of
the nature of chlorine. In the progress of that train of enquiry,
which became necessary for the adjustment of our views as they
regarded the combinations of that body, Davy discovered a series of
new compounds, the history of which he communicated in successive
papers to the Royal Society.
In a memoir read in February 1811, entitled, "On a Combination
of Oxymuriatic Gas and Oxygen Gas," he announced the existence
of a _protoxide_ of chlorine, under the name of _Euchlorine_;
and in a communication from Rome in the year 1815, he described
another compound of chlorine and oxygen, containing a still larger
proportion of this latter element, and which has since been made
the subject of a series of experiments by Count Stadion of Vienna.
As it does not exhibit any acid properties, Dr. Henry proposes
to call it a _Peroxide_, in preference to _Deutoxide_; thinking
it probable that intermediate compounds, between this and the
protoxide already mentioned, may be hereafter discovered.
His paper on _euchlorine_ abounds with interest. He found that
by acting on the salts formerly denominated _hyper-oxymuriates_,
by muriatic acid, the gas evolved differed very greatly in its
properties, with the different modes of preparing it. When
much acid was employed with a small quantity of the salt, and
the gas was collected over water, it was not found to differ
from oxymuriatic gas; but when, on the other hand, the gas was
procured by means of a weak acid, and a considerable excess of
the salt, at a low heat, and was collected over mercury, it
possessed properties essentially different. Its colour, under such
circumstances, was of a dense tint of brilliant yellow-green,
whence the name of _euchlorine_.[90] When in a pure form, this gas
is so readily decomposed, that it will sometimes explode during the
time of its transfer from one vessel to another, producing both
heat and light with an expansion of volume,[91] and it may always
be made to explode by a very gentle heat, often even by that of the
hand.
[90] From [Greek: eu] and [Greek: chlôros].
Public-domain text, read in full here on John Shaqi.
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