The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In his Bakerian Lecture of 1810, entitled, "On some of the
Combinations of Oxymuriatic Gas and Oxygen, and on the Chemical
Relations of these Principles," he details a number of experiments
for the illustration of this subject, and arrives at the
conclusion, that the oxygen in the hyper-oxymuriate of potash is
in triple combination with the metal and chlorine. He likewise
confirms his views, with regard to the elementary nature of
this latter body, by a series of new enquiries, and shows that
they are not incompatible with known phenomena:--for instance,
Scheele explained the bleaching powers of oxymuriatic gas, by
supposing that it destroyed colours by combining with _Phlogiston_.
Berthollet[87] considered it as acting by imparting oxygen; Davy
now proves that the pure gas is wholly incapable of altering
vegetable colours, and that its operation in bleaching entirely
depends upon its property of decomposing water, and of thus
liberating its oxygen.[88] The experiment by which he demonstrated
this fact is so simple and satisfactory, that I shall here relate
it. Having filled a glass globe, containing dry powdered muriate of
lime, with oxymuriatic gas, he introduced into another globe, also
containing muriate of lime, some dry paper tinged with litmus,
that had been just heated; by which device the intrusion of
moisture was effectually prevented. After some time, this latter
globe was exhausted, and then connected with that containing the
oxymuriatic gas, and by an appropriate set of stop-cocks, the paper
was exposed to the action of the gas thus dried: no change of
colour in the test paper took place, and after two days, there was
scarcely a perceptible alteration; while some similar paper dried
and introduced into the gas, that had not been exposed to muriate
of lime, was instantly bleached.
[87] Berthollet first applied oxymuriatic acid for the purpose
of bleaching, in France; from whence Mr. Watt introduced it into
England.
[88] Dr. Thomson has more recently explained the operation,
by supposing that water is decomposed, and that its hydrogen
goes to the chlorine, and its oxygen to the water, forming with
the latter a deutoxide of hydrogen, or the oxygenated water of
Thénard, which he considers as the true bleaching principle.
As an illustration of the eagerness with which he seized upon
facts, in order to apply them to economical purposes, it may be
stated that, on reflecting upon the theory of bleaching, and on
the changes which its agents undergo, he was led to propose the
use of a liquor produced by the condensation of oxymuriatic gas in
water, containing magnesia diffused through it, as superior to the
oxymuriate of lime commonly employed.[89]
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