The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The same metal is also capable of uniting with different
proportions of chlorine, which, so far as has been yet ascertained,
are definite, and in no case exceed two proportions to one of
metal. Hence it was proposed by Davy, in fixing the nomenclature of
these compounds, to designate such as contain the least proportion
of chlorine by the termination _ane_, added to the Latin name
of the metal, as _cuprane_ for that of copper; those containing
the larger proportion of chlorine, by the termination _anea_,
as _cupranea_. The chemical name of our common culinary salt,
in conformity with such a nomenclature, would be _sodane_. This
proposition, however, has not been adopted;[92] the compounds
of metals and chlorine are either called _chlorurets_, or what
is preferable, from their analogy with the similar compounds
of oxygen, _chlorides_, and which are further distinguished as
_protochlorides_, _deutochlorides_, &c.
[92] A little reflection will convince us that such a
nomenclature could never have been adopted with propriety. It
is in direct defiance of the Linnæan precept, that a specific
name must not be united to the generic as a termination; besides
which, such terms could never have been preserved in translations
into other languages.
In connexion with the history of these chlorides, a question
arises of great interest and obscurity, and which has engaged the
attention of some of our most distinguished chemists,--whether
such a body, when dissolved by water, remains as a chloride; or,
by decomposing that fluid, and combining with its elements, is
not immediately converted into a muriate? With respect to several
of these chlorides, no doubt can be entertained as to the fact of
their decomposing water; for instance, the chloride of phosphorus
is thus acted upon, the oxygen of the water forms phosphorous acid
with the phosphorus, while its hydrogen unites with the chlorine
to form muriatic acid; and as those products are such as do not
combine with each other, but exist in a state of mixture in the
water, each may be recognised by its peculiar properties. In like
manner, as Davy has observed, when water is added in certain
quantities to Libavius's liquor (_deutochloride of tin_), a solid
crystalline mass is obtained, from which oxide of tin and muriate
of ammonia can be obtained by ammonia.
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