The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In his Elements of Chemical Philosophy, Davy has been, in many
instances, explicit on this point; and his opinions are favourable
to the idea that chlorides become muriates by being dissolved in
water: thus, he states that the perchloride of iron "acts with
violence upon water, and forms a solution of red muriate of iron;"
and he observes that the permuriate "forms a solution of green
muriate of iron by its action upon water."[93] With regard,
however, to the general principle, that chlorides become muriates
by solution, there are difficulties which do not fall within
the province of a biographer to discuss. I shall merely observe
that such a change is, in many cases, so inconsistent with our
preconceived opinions, that very strong evidence is required to
reconcile us to its truth. We are undoubtedly prepared to hear that
much may happen between the cup and the lip,--but that common salt
should be a _chloride of sodium_ on our plates, and a _muriate of
soda_ in our mouths, is certainly a very startling assertion.
[93] For an admirable paper upon this subject by Mr. R. Phillips,
in which all the material points of the subject are considered
with that acumen which distinguishes its author, see Annals of
Philosophy, vol. i. New Series.
The reception which the chloridic theory met with from the chemical
world might aptly enough be adduced in illustration of that remark
with which I commenced the preceding chapter. At first, its
truth was questioned, and no sooner had this been triumphantly
established, than an attempt was invidiously made to transfer the
glory of the discovery from Davy to the French philosophers. Upon
each of these points, I shall beg to offer a few observations.
First, with regard to the fact of chlorine being as yet an
undecompounded body. The very announcement of a theory so
adverse to the universal faith of Europe, was a signal for open
hostilities; the observations of Dr. Murray may be considered as
expressing the sentiments of most of the leading chemists on the
first publication of the novel views of Davy. "Opinions," says
he, "more unexpected have seldom been announced to chemists, than
those lately advanced by Mr. Davy with regard to the constitution
of the muriatic and oxymuriatic acids; _viz._ that the latter is
not a compound of muriatic acid and oxygen, but a simple substance,
and that the former is a compound of this substance with hydrogen.
The more general principle connected with these opinions, that
oxymuriatic acid is, like oxygen, an acidifying element, forming
with inflammables and metals an extensive series of analogous
compounds, leads still more directly to the subversion of the
established chemical systems, and to an entire revolution in some
of the most important doctrines of the science."
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