The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
reasonably be referred to a minute quantity of vapour in the gases,
or to a little moisture derived from the mercury, a small quantity
of which entered the retort with the gases. Dr. Hope wished to
ascertain how much water would produce such a dew as was observed.
For this purpose he heated in a retort, of a similar size to that
used in the experiment, a single drop of water, which it may be
said weighs about a grain. The appearance of condensed water, in
this instance, in the neck of the retort, was much greater than in
the preceding: he considered it as being three or four times as
great.[94]
[94] Sir Humphry Davy, during some experiments on the diamond,
subsequently ascertained that less than 100th of a grain of water
is sufficient to produce a sensible dew on a polished surface.
From these results it may be concluded, on Dr. Murray's own ground
of reasoning, that water is not a constituent part of muriatic
acid gas, and that this substance is a compound merely of chlorine
and hydrogen; for it is easy to account for the presence of about
one-third of a grain of water from various sources, while it is
impossible to account for the absence of eight grains upon any
theory except that which supposes the gas to be _anhydrous_.
I shall not pursue the numerous other experiments by which it was
attempted to prove the fallacy of Davy's views; they all turn upon
the same point, and were refuted by the same vigorous methods of
enquiry. The chloridic theory may therefore now be considered as
fully established: the philosophers who were for so long a period
hostile to its reception, have at length yielded their assent; and
Berzelius, in a paper published in the "Annales de Chimie," on the
subject of sulpho-cyanic acid, has unconditionally tendered his
allegiance; while the subsequent discovery of iodine and bromine
has confirmed, by the most beautiful analogies, the views so
satisfactorily explained by experiment.
As to the claim of priority which has been urged by several
philosophers in favour of the French chemists, Davy, in speaking
of Gay Lussac's paper, published in the "Annales de Chimie" for
July 1814, observes, that "the historical notes attached to it are
of a nature not to be passed over without animadversion. M. Gay
Lussac states, that he and M. Thénard were the first to advance
the hypothesis that chlorine was a simple body; and he quotes M.
Ampère as having entertained that opinion before me. On the subject
of the originality of the idea of chlorine being a simple body, I
have always vindicated the claims of Scheele; but I must assume
for myself the labour of having demonstrated its properties and
combinations, and of having explained the chemical phenomena it
produces; and I am in possession of a letter from M. Ampère, that
shows he has no claims of this kind to make."[95]
[95] Royal Institution Journal, vol. i. p. 283.
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