The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Dr. Murray entered the lists as the avowed partisan of the theory
of Berthollet; Dr. Davy, on the other hand, appeared as the
champion of his brother's doctrine. A severe contest ensued, and
both combatants displayed equal skill and strength. The object
of the former was to demonstrate the presence of water, or its
elements, as a constituent part of muriatic acid; and he proposed
to determine the point by combining the dry gases of muriatic acid
and ammonia; for as these bodies did not contain its elements,
should water appear, he maintained that it must be considered as
pre-existing in the muriatic acid; while, on the contrary, if no
water could be procured, it would be unphilosophical to suppose
it present, but that muriatic acid gas must, in that case, be
considered as a compound of hydrogen and chlorine. In performing
this experiment, Dr. Murray did succeed in obtaining a portion of
water; but the inference from such a fact was questioned on the
other side, upon the assumption of the humidity of the gases. As
all parties, however, seemed to agree, that if every source of
error could be excluded, the combination of these gases would
furnish an _experimentum crucis_, by which the truth or fallacy
of either theory might be established, Davy, when at Edinburgh,
was desirous of repeating the experiment with Dr. Hope, and it was
accordingly made in the College Laboratory. Sir George Mackenzie,
Mr. Playfair, and some other gentlemen, were present. The results
were communicated in Nicholson's Journal by Dr. Davy, and may be
briefly stated as follows:--The alkaline and acid gases were pure,
and both had been previously dried by exposure for sixteen hours
to substances having a strong attraction for water. The apparatus
consisted of a plain retort of about the capacity of twenty-six
cubic inch measures, with a stop-cock; and of a receiver, with a
suitable stop-cock. The latter was filled over mercury with one
of the gases, which from the receiver passed into the exhausted
retort by means of the stop-cocks; the other gas was introduced the
same way into the retort; and thus alternately about ninety cubic
inches of each gas were combined. All the salt having then been
driven into the bulb of the retort by the heat of a spirit lamp,
the neck was cooled and kept cold by moistened cloths, whilst the
bulb was heated by a coke fire, till the muriate began to sublime,
and to make its appearance at the curvature of the vessel when
the fire was withdrawn. The result was then examined, while the
bottom of the retort was still very hot: a dew, just perceptible,
was observed lining the cold neck. The quantity of water was so
extremely small, that the globular particles composing this dew
could scarcely be perceived by the naked eye; now the quantity
of water, according to hypothesis, should equal no less than
eight grains. There is no small difference, it must be confessed,
between that quantity and a dew barely perceptible, and which may
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account