The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
On experimenting upon this latter body with water, he obtained a
crystallized substance which he proposed to call _Hydro-phosphorous
acid_, since it consists of pure phosphorous acid and water. By
decomposition in close vessels, it is resolved into phosphoric
acid, and a peculiar gas, consisting of one proportional of
phosphorus and four of hydrogen, and for which he proposed the term
_Hydro-phosphorous_ gas. The reader, no doubt, will be immediately
struck with the impropriety of a nomenclature in which the prefix
_Hydro_ is made to express water in the former, and hydrogen in the
latter instance.
In examining the results of the mutual decomposition of water and
the phosphoric compounds of chlorine, Davy remarks, that it is
scarcely possible to imagine more perfect demonstrations of the
laws of definite combination: no products are formed except the
new combinations, (phosphoric acid from the solid, phosphor_ous_
acid, from the liquid compound, and in both muriatic acid;)
neither oxygen, hydrogen, chlorine, nor phosphorus, is disengaged;
and therefore the ratio in which any two of them combine being
known, the ratio in which the rest combine, in these cases, may be
determined by calculation.
Lastly, he ascertained that most of the substances obtained by
precipitation from aqueous solutions are compounds of water: thus
zircona, magnesia, and silica, when precipitated and dried at 212°,
still contain definite proportions of water; and many of the
substances which had been considered as metallic oxides, he found,
when obtained from solutions, to agree in this respect; and that
their colours and other properties are materially influenced by
this combined water.
On the 5th of November 1812, was read before the Royal Society a
letter addressed by Davy to Sir Joseph Banks, on the subject of the
detonating compound already alluded to in his communications to
Mr. Children. He expresses his anxiety to have the circumstances
made public as speedily as possible, since experiments upon the
substance may be connected with very dangerous results.
He had some time before received information from Paris of a
combination having been effected between chlorine and azote, and
that it was distinguished by detonating properties; but he was
wholly ignorant of the mode by which it had been prepared, and he
could not obtain any information upon this point from any of the
French journals.
Public-domain text, read in full here on John Shaqi.
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