The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
So curious and important a result could not fail to interest him,
as he had himself been long engaged in experiments on the action
of azote and chlorine, without gaining any decided proofs of
their power of combining with each other. It was evident from the
notice, that this new body could not be formed in any operations
in which heat is concerned; he therefore attempted to combine the
elements by presenting them to each other artificially cooled, the
azote being in a nascent state. For this purpose he introduced
chlorine into a solution of ammonia; a violent action ensued, and
minute films of a yellow colour were observed on the surface of
the liquor, but they immediately resolved themselves into gas. As
he was about to repeat the experiment with some other ammoniacal
compounds, Mr. Children reminded him of the circumstance which he
had previously communicated to him in a letter, that Mr. James
Burton, junr, on exposing chlorine to a solution of nitrate of
ammonia, had observed the formation of a yellow oil, but which he
had not been able to collect. Davy availed himself of the hint, and
obtained the substance in question: on examining its properties by
the application of heat, the tube in which it was contained was
shivered to atoms by its explosion, and he received a severe wound
in the transparent cornea, which was followed by inflammation, and
disabled him from pursuing his enquiry.
In the following July, however, he communicated in a second
letter to Sir Joseph Banks, the continuation of this enquiry, and
furnished a full and satisfactory history of the body in question.
Having procured it in sufficient quantity, he attempted to effect
its analysis by the action of mercury, but a violent detonation
occurred, and he was again wounded in the head and hands;
fortunately, however, the injury was slight, in consequence of his
having taken the precaution to defend his face by a plate of glass
attached to a proper cap.
In a subsequent experiment, by using smaller quantities, and
recently distilled mercury, he succeeded in obtaining results
without any violence of action: the mercury united with the
chlorine, and the azote was disengaged; from which he was enabled
to conclude that it was composed of four volumes of chlorine and
one volume of azote. For this new body Davy suggested the name of
_Azotane_; but I have already observed, that his nomenclature of
the compounds of chlorine has never been adopted; the detonating
substance is now very properly denominated _Chloride of Nitrogen_.
Shortly after the publication of this paper, M. Berzelius, in a
letter to Professor Gilbert, asserted that "_Azotane_" is nothing
more than _dry_ nitro-muriatic acid, since it dissolves slowly in
water, and forms a weak _aqua regia_. "These few observations,"
says he, "show clearly that Davy's analysis of this substance is
inaccurate, and that he corrected his results in consequence of
theoretical views."
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