The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
When he considered that copper is but weakly positive in the
electro-chemical scale, and that it can only act upon sea-water
when in a positive state, it immediately occurred to him that, if
it could be rendered slightly negative, the corroding action of
sea-water upon it would be null. But how was this to be effected?
At first, he thought of using a Voltaic battery; but this could
hardly be applicable in practice. He next thought of the contact of
zinc, tin, or iron; but he was prevented for some time from trying
this, by the recollection that the copper in the Voltaic battery,
as well as the zinc, was dissolved by the action of dilute nitric
acid; and by the fear, that too large a mass of oxidable metal
would be required to produce decisive results. After reflecting,
however, on the slow and weak action of sea-water on copper, and
the small difference which must exist between their electrical
powers; and knowing that a very feeble chemical action would be
destroyed by a very feeble electrical force, he was encouraged to
proceed; and the results were highly satisfactory and conclusive. A
piece of zinc, not larger than a pea, or the point of a small iron
nail, was found fully adequate to preserve forty or fifty square
inches of copper,--and this, wherever it was placed, whether at the
top, bottom, or in the middle of the sheet of copper, and whether
the copper was straight or bent, or made into coils. And where the
connexion between the different pieces of copper was completed by
wires, or thin filaments of the fortieth or fiftieth of an inch in
diameter, the effect was the same; every side, every surface, every
particle of the copper, remained bright; whilst the iron, or the
zinc, was slowly corroded.
A piece of thick sheet copper, containing on both sides about sixty
square inches, was cut in such a manner as to form seven divisions,
connected only by the smallest filaments that could be left, and
a mass of zinc, of the fifth of an inch in diameter, was soldered
to the upper division. The whole was plunged under sea-water;
the copper remained perfectly polished. The same experiment was
repeated with iron, and after the lapse of a month, the copper was
in both instances found as bright as when it was first introduced;
whilst similar pieces of copper, undefended, underwent in the same
water very considerable corrosion, and produced a large quantity of
green deposit in the bottom of the vessel.
Numerous other experiments were performed, and with results equally
conclusive of the truth of the theory which had suggested them.
Public-domain text, read in full here on John Shaqi.
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