The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
On keeping a polished piece of copper in contact with sea-water,
the following were the effects which successively presented
themselves. In the course of two or three hours, the surface of
the metal exhibited a yellow tarnish, and the water in which it
was immersed contracted a cloudiness, the hue of which was at
first white, but gradually became green. In less than a day, a
bluish-green precipitate appeared, and constantly continued to
accumulate in the bottom of the vessel; at the same time, the
surface of the copper corroded, appearing red in the water, and
grass-green where it was in contact with air. Upon this grass-green
matter carbonate of soda formed; and these changes continued
until the water became much less saline. The green precipitate he
ascertained to consist of an insoluble compound of copper, (which
he thinks may be considered as a _hydrated sub-muriate_,) and
hydrate of magnesia.[92]
[92] The Muriate of Magnesia is the most active salt in sea-water.
According to his own views of the nature of chlorine, he
immediately perceived that neither soda nor magnesia could appear
in sea-water by the action of a metal, unless in consequence of an
absorption or transfer of oxygen, which in this case must either be
derived from the atmosphere, or from the decomposition of water:
his experiments determined that the former was the source which
supplied it. By reasoning upon these phenomena, and applying for
their explanation his electro-chemical theory, which had shown
that chemical attractions may be exalted, modified, or destroyed,
by changes in the electrical states of bodies, he was led to the
discovery of a remedy for the corrosion of copper, by the very
principle which enabled him, sixteen years before, to decompose the
fixed alkalies.
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