The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
A series of very interesting experiments, fully detailed in this
memoir, which were instituted for the purpose of ascertaining the
extent of the diminution of electrical action in instances of
imperfect or irregular conducting surfaces, led him to the general
conclusion, that a very small quantity of the imperfect or fluid
conductor was sufficient to transmit the electrical power, or to
complete the chain. This induced him to try whether copper, if
nailed upon wood, and protected merely by zinc or iron on its
_under_ surface, or on that next the wood, might not be defended
from corrosion: a question of great practical moment with regard
to the arrangement of protectors. For this purpose, he covered
a piece of wood with small sheets of copper, a nail of zinc of
about 1/100 part of the surface having been previously driven
into the wood: the copper surface remained perfectly bright in
sea-water for many weeks; and when the result was examined, it
was found that the zinc had only suffered partial corrosion; that
the wood was moist, and that, on the interior of the copper there
was a considerable portion of revived zinc, so that the negative
electricity, by its operation, provided materials for its future
and constant excitement. In several trials of the same kind, iron
was used with similar results; and in all these experiments there
appeared to be this peculiarity in the appearance of the copper,
that unless the protecting metal below was in a large mass, there
were no depositions of calcareous or magnesian earths upon the
metal; it was clean and bright, but never coated. The copper in
these experiments was nailed sometimes upon paper, sometimes upon
the mere wood, and sometimes upon linen; and the communication was
partially interrupted between the external and internal surfaces by
cement; but even one side or junction of a sheet seemed to allow
sufficient communication between the moisture on the under surface
and the sea-water without, to produce the electrical effect of
preservation. This last experiment of Davy is of greater importance
than may at first appear, in showing what a small proportion of
conducting fluid will complete a circuit, and in thus explaining
phenomena, as I shall presently show, which might not otherwise be
suspected to have an electrical origin.
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