The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
These results upon perfect and imperfect conductors led him
to another enquiry, important as it relates to the practical
application of the principle, namely, as to the extent and nature
of the contact or relation between the copper and the preserving
metal. He was unable to produce any protecting action of zinc
or iron upon copper through the thinnest stratum of air, or the
finest leaf of mica, or of dry paper; but the action of the metals
did not seem to be much impaired by the ordinary coating of
oxide or rust; nor was it destroyed when the finest bibulous, or
_silver-paper_, as it is commonly called, was between them, being
moistened with sea-water. He made an experiment with different
folds of this paper. Pieces of copper were covered with one, two,
three, four, five, and six folds; and over them were placed pieces
of zinc, which were fastened closely to them by thread; each piece
of copper, thus protected, was exposed in a vessel of sea-water, so
that the folds of paper were all moist.
It was found in the case in which a single leaf of paper was
between the zinc and the copper, there was no corrosion of the
copper; in the case in which there were two leaves, there was a
very slight effect; with three, the corrosion was distinct; and it
increased, till with six folds the protecting power appeared to
be lost; and in the case of the single leaf, the result differed
only from that produced by immediate contact, in there not being
any deposition of earthy matter. Other experiments likewise proved
that there was no absolute contact of the metals through the moist
paper; for, although a thin plate of mica, as before stated,
entirely destroyed the protecting effect of zinc, yet when a hole
was made in it, so as to admit a very thin layer of moisture
between the zinc and copper, the corrosion of the latter, though
not prevented, was considerably diminished.
The experimental part of this paper concludes with an account of
various trials to determine the electro-chemical powers of metals
in menstrua out of the contact, or to a certain extent removed
from the contact of air; in order, if possible, to diminish the
rapid waste of the protecting metals. In the progress of these
experiments he exhibits, in a most beautiful manner, the singular
effect of different proportions of a fixed alkali, when mixed with
sea-water, in rendering the iron, in its Voltaic connection with
copper, more or less negative.
He terminates the paper with some observations of a practical
nature, relative to the best modes of rendering iron applicable
to the purposes of protection; but, as these have been already
embodied in the investigation, it is not necessary to notice them
farther in this place.
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