The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
My attention has for several years been directed to the state of
the water with which the metropolis is supplied; and upon having
been lately requested to propose a remedy for preventing the
action of a spring in the neighbourhood of London upon lead, which
it had been found to corrode in a very rapid manner, I suggested
the expediency of protecting the pipes and cisterns with surfaces
of iron; but before such a plan was put in execution, I proposed
to try its efficacy in the laboratory:--the first result was very
startling; for, instead of preventing, as I had anticipated, I
found that it greatly increased, the solution of the lead. After
various experiments, I arrived at the conclusion, that lead, when
rendered negative by iron, and placed in contact with weak saline
solutions,--such, for instance, as common spring water,--was
dissolved; in consequence of the decomposition of the salts and
the transference of their elements according to the general law,
the acid passing to the iron, and the alkali to the lead; and so
powerfully is this latter body acted upon by an alkali, that, if
a slip of it be immersed in a solution of potash or soda, its
crystalline texture is so rapidly developed, that its surface
exhibits an appearance similar to that presented by tin-plate, and
which is designated by the term _moirée_.
I apprehend that most of the anomalous cases of the solution of
lead in common water, which have for so many years embarrassed the
chemist, may thus receive an explanation. An eminent physician
lately informed me, that some time since he was called upon to
attend a family who had evidently suffered from the effects of
saturnine poison, and that he well remembers there was an iron
pump in the cistern that supplied the water. Upon showing the
results of my experiment to a no less eminent chemist, he was
immediately reminded of a circumstance which occurred at Islington,
where the water was found to corrode the lead in which it was
received: in this vessel there was an iron bar; and the fact would
not have attracted his notice, nor have been impressed upon his
recollection, but from the unusual state of corrosion in which it
appeared.
I shall conclude these observations by an account of "the change
which some musket balls, taken out of Shrapnell's shells, had
undergone," by Mr. Faraday, and which is published in the 16th
volume of the Quarterly Journal of Science, for the year 1823. This
history is not only interesting on account of the high chemical
character of its author, but satisfactory as being in direct
opposition to previously established facts; and cannot therefore
have received any bias from preconceived theory.
Public-domain text, read in full here on John Shaqi.
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