The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
"Mr. Marsh of Woolwich gave me some musket balls, which had been
taken out of Shrapnell's shells. The shells had lain in the
bottoms of ships, and probably had sea-water amongst them. When
the bullets are put in, the aperture is merely closed by a common
cork. These bullets were variously acted upon: some were affected
only superficially, others more deeply, and some were entirely
changed. The substance produced is hard and brittle; it splits
on the ball, and presents an appearance like some hard varieties
of hæmatite; its colour is brown, becoming, when heated, red; it
fuses on platinum foil into a yellow flaky substance like litharge.
Powdered and boiled in water, no muriatic acid or lead was found in
solution. It dissolved in nitric acid without leaving any residuum,
and the solution gave very faint indications only of muriatic
acid. It is a _protoxide of lead_, perhaps formed, in some way, by
the galvanic action of the iron shell and the leaden ball, assisted
probably by the sea-water. It would be very interesting to know the
state of the shells in which a change like this has taken place
to any extent. _It might have been expected, that as long as any
iron remained, the lead would have been preserved in the metallic
state._"
In one experiment, I found that a piece of lead protected by iron
underwent solution in water containing nitrate of potash, while it
resisted the action of very dilute nitric acid: upon this point,
however, farther enquiry is necessary; for I subsequently failed in
producing the same effect, owing, no doubt, to having employed too
strong an acid.
Let us return from this digression to the subject of Sir Humphry
Davy's Protectors. It only remains for me to relate the results
which followed the practical application of the Voltaic principles
which his various experiments had developed.
In the month of May 1824, directions were issued by the Lords of
the Admiralty to protect, in future, the copper sheathing of all
his Majesty's ships which might be taken into dock, upon the plan
proposed by Sir Humphry Davy.
The protectors were bars of iron six inches wide at their base,
three inches in thickness in their centre, and, in outward form,
the segment of an extended circle. They were usually placed on each
side of the ship in a horizontal position, viz. in midships about
three feet under water--on the keel in a line with these--and the
remainder in the fore and afterparts of the ship (about three feet
under the line of fluitation), as far forward and abaft as the
curvatures of their respective bodies would allow of their lying
flat upon the surface of the copper.
As it is difficult by verbal description alone to convey a
sufficiently distinct idea of this subject to persons unacquainted
with naval architecture, I have introduced a sketch, exhibiting
the _general_ position of the _Protectors_, although they are
necessarily exaggerated in size, or they would have appeared as
mere specks upon the drawing.
Public-domain text, read in full here on John Shaqi.
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