The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The discovery of the gases, of a new class of bodies more active
than any others in most of the phenomena of nature and art, could
not fail to modify the whole theory of chemistry, and, under the
genius of Lavoisier, it ultimately led to the establishment of
those new doctrines, which it is the principal object of this
history to expound; but before this task can be accomplished, it
will be necessary to consider the rise and progress of opinion
concerning chemical attraction, and heat and light, since these
subjects are too intimately interwoven with the _anti-phlogistic_
system to be separated from any examination of its principles.
Boyle, says Sir Humphry Davy, was one of the most active
experimenters, and certainly the greatest chemist of his age. He
introduced the use of _tests_, or _re-agents_, active substances
for detecting the presence of other bodies: he overturned the ideas
which at that time were prevalent, that the results of operations
by fire were the real elements of things; and he ascertained a
number of important facts respecting inflammable bodies, and
alkalies, and the phenomena of combination; but neither he nor any
of his contemporaries endeavoured to account for the changes of
bodies by any fixed principles.
The solutions of the phenomena were attempted either on rude
mechanical notions, or by occult qualities, or peculiar subtile
spirits or ethers, supposed to exist in the different bodies. And
it is to the same great genius who developed the laws that regulate
the motions of the heavenly bodies, that chemistry owes the first
distinct philosophical elucidations of the powers which produce the
changes and apparent transmutations of the substances belonging to
the earth.
"Sugar dissolves in water, alkalies unite with acids, metals
dissolve in acids. Is not this," says Newton, "on account of an
attraction between their particles? Copper dissolved in aqua fortis
is thrown down by iron. Is not this because the particles of the
iron have a stronger attraction for the particles of the acid, than
those of copper; and do not different bodies attract each other
with different degrees of force?"
In 1719, Geoffroy endeavoured to ascertain the relative attractive
powers of bodies for each other, and to arrange them, under the
form of a table, in an order in which these forces, which he named
affinities, were expressed.
Concerning the nature of heat, there are two opinions which have
ever divided the chemical world. The one considers it merely as a
property of matter, and that it consists in an undefinable motion,
or vibration of its particles; the other, on the contrary, regards
it as a distinct and subtile substance, _sui generis_. Each of
these opinions has been supported by the greatest philosophers,
and for a long period the arguments on both sides appeared equally
plausible and forcible. The discovery of Dr. Black, however, gave a
preponderance to the scale in favour of its materiality.
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