The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
"It was during his residence in Glasgow, between the year 1759
and 1763," says Dr. Thomson, "that he brought to maturity those
speculations concerning the combination of _heat_ with _matter_,
which had frequently occupied a portion of his thoughts."
Before Dr. Black's discovery, it was universally supposed that
solids were converted into liquids by a small addition of heat,
after they have been once raised to the melting point, and
that they returned again to the solid state on a very small
diminution of the quantity of heat necessary to keep them at
that temperature. An attentive view, however, of the phenomena
of liquefaction and solidification gradually led this sagacious
philosopher to a different conclusion. By observations which
it is unnecessary to detail, he became satisfied that when ice
is converted into water, it unites with a quantity of heat,
without having its temperature increased; and that when water
is frozen into ice, it gives out a quantity of heat without
having it diminished. The heat thus combined, then, is the cause
of the fluidity of the water; and as it is not sensible to the
thermometer, Dr. Black called it _latent heat_.
There is such an analogy between the cessation of thermometric
expansion during the liquefaction of ice, and during the conversion
of water into steam, that there could be no hesitation about
explaining both in the same way. Dr. Black, therefore, immediately
concluded that, as water is ice united to a certain quantity of
_latent_ heat, so steam is water united to a still greater quantity.
This beautiful theory enables us to understand phenomena in nature
which were previously quite inexplicable. We now comprehend how the
thaw which supervenes after intense frost, should so slowly melt
the wreaths of snow and beds of ice. Had, indeed, the transition
of water from its solid into its liquid state not been accompanied
by this great change in its relation to heat, every thaw would
have occasioned a frightful inundation, and a single night's frost
must have solidified our rivers and lakes. Neither animal nor
vegetable life could have subsisted under such sudden and violent
transitions. It would appear, then, that water, during the act of
freezing, is acted upon by two opposite powers: it is deprived of
heat by exposure to a medium whose temperature is below 32°; and
it is supplied with heat by the evolution of that principle from
itself, _viz._ of that portion which constituted its fluidity. As
these powers are exactly equal, the temperature of the water must
remain unchanged till the latent heat, necessary to its fluidity,
is all evolved.
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