The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
He tells us that he had long felt a desire to make some new
experiments on the combustion of the diamond and other carbonaceous
substances; and that this desire was increased by the new fact
ascertained with respect to iodine, which by uniting to hydrogen,
affords an acid so analogous to muriatic acid, that it was for
some time confounded with that body. His object in these new
experiments, was to examine minutely whether any peculiar matter
was separated from the diamond during its combustion, and to
determine whether the gas, formed in this process, was precisely
the same in its minute chemical nature, as that formed in the
combustion of common charcoal. By his experiments at Florence, he
satisfactorily accomplished his wishes, and established beyond a
question the important fact, that "the diamond affords no other
substance by its combustion than pure carbonic acid gas; and that
the process is merely a solution of diamond in oxygen, without any
change in the volume of the gas."
As one of the principal objects in these researches was to
ascertain whether water was formed during the combustion of the
diamond, with a view to decide the question of the presence of
hydrogen, every possible source of fallacy was excluded. In one
experiment there was an evident deposition of moisture, but it was
immediately discovered to have been owing to the production of
vapour from a cork connected with a part of the apparatus, during
the combustion.
In the progress of this research, he ascertained a fact, the
knowledge of which must not only be considered as important to the
present enquiry, but as highly valuable in excluding error from our
reasonings upon the delicate results of analysis[13]--I allude to
the extremely minute quantity of water which becomes perceptible
by deposition on a polished glass surface. He introduced a piece
of paper weighing a grain into a tube of about the capacity of
four cubical inches, the exterior of which was gently heated by a
candle; immediately a slight but perceptible dew appeared in the
interior of the upper part of the tube; the paper taken out and
directly weighed in a balance, sensible to 1-100th of a grain, had
not suffered any appreciable diminution. If, then, on burning 1·84
grains of diamond in oxygen gas, not even a barely perceptible
dew was produced, we may consider it as fully proved that this
gem cannot contain hydrogen in its composition: but to render the
demonstration, if possible, still more complete, he kept a small
diamond, weighing ·45 of a grain, in a state of intense ignition
by the great lens of the Florentine Museum, for more than half an
hour, in chlorine; but the gas suffered no change, and the diamond
underwent no alteration either in weight or appearance: now had
the smallest portion of hydrogen been developed, white fumes of
muriatic acid would have been visible, and a certain condensation
of the gas must have taken place.
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