The London Mercury, Vol. I, Nos. 1-6, November 1919 to April 1920Various
General
The London Mercury, Vol. I, Nos. 1-6, November 1919 to April 1920
Various
English literature -- Periodicals; London (England) -- Periodicals
There are many chemical reactions which are promoted or accelerated by
the addition of a small quantity of some foreign substance which is not
used up in the process and does not appear in the final products. Thus
one of the romances of chemistry was the discovery, occasioned by the
chance breaking of a thermometer in the vessel, that the presence of a
small quantity of mercury greatly hastens the oxidation of naphthalene
to phthalic acid, a process of great importance in the manufacture
of synthetic indigo. Similarly the presence of finely divided metals
accelerates many reactions, such as oxidations and hydrogenations--for
example, asbestos impregnated with particles of platinum promotes
the oxidation of sulphur dioxide to the trioxide in the manufacture
of sulphuric acid. The researches of Baker and others, showing that
certain gas reactions, which ordinarily take place rapidly, proceed
very slowly indeed if the gases are thoroughly dried, point to a
catalytic action of small traces of moisture. The enzymes of the
human body which accelerate the chemical processes of digestion and
assimilation constitute another class of catalysts, and Drs. Rideal and
Taylor class under catalytic action the effect of radiant energy in
promoting such combinations as that of hydrogen and chlorine, although
it is perhaps rather extending the usual conception of the term to do
so. These examples will indicate the wide range of the subject and
help to make intelligible Ostwald's famous generalisation that "there
is probably no kind of chemical reaction which cannot be influenced
catalytically, and there is no substance, element, or compound which
cannot act as a catalyser," which is no doubt true if very slight
accelerations of reaction be taken into account. Of course a catalyst
cannot affect the final state of equilibrium, but only quicken or
institute (the discussion as to whether, in some cases, the catalyst
initiates or merely accelerates a reaction already taking place
imperceptibly slowly seems to us pointless) a reaction theoretically
possible. Other, the so-called negative, catalysts hinder reactions;
other substances "poison," or stop, the action of ordinarily activating
materials; others again, the "promoters," increase the efficacy of the
catalyst. The phenomenon is a complex one.
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