The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
Green earth is a valuable pigment for all kinds of painting, on account
of its extreme permanence. It may be applied directly over lime without
suffering any change, whereas most of the cheap green colours are
destroyed in like circumstances. This behaviour renders green earth
specially valuable in fresco work, although it is also largely used as
an oil colour.
Augite is of frequent occurrence in volcanic districts; and in such
localities, deposits of green earth are certain to be found. The test
for the suitability of a green earth consists mainly in treatment
with dilute hydrochloric acid. If the mineral assumes a handsome
green tone, it will generally form a useful pigment. The test may be
supplemented by applying the colour to a fresh coating of whitewash,
under which conditions it should remain unaltered.
ARTIFICIAL GREEN EARTH (GREEN OCHRE)
A product sometimes put on the market as green earth or green ochre has
nothing beyond its name in common with green earth properly so called,
except a certain similarity in colour. This pigment is prepared by
mixing yellow ochre to a thin pulp with water and adding about 2% (of
the weight of ochre) of hydrochloric acid. After a few days, a solution
of 2 parts of yellow prussiate of potash is added, and if the liquor
still gives a precipitate when tested with ferrous sulphate, this
last-named salt is added so long as such a precipitate continues to
form.
The deposit is washed, and dried in the ordinary way. When the right
proportions have been taken, a pigment is obtained that coincides
fairly in point of tone with true Verona earth. It is, however,
inferior in point of permanence, the Berlin blue present being somewhat
unstable and decomposing very quickly when brought into contact
with lime. The reaction taking place in the production of so-called
“artificial Celadon green” is that the hydrochloric acid used dissolves
ferric oxide from the ochre, the addition of the yellow prussiate of
potash then forming a blue precipitate of Berlin (Paris) blue which,
in conjunction with the yellow of the ochre, gives a green-coloured
mixture.
MALACHITE GREEN
Although the pigment sold under this name is nearly always an
artificial product, it cannot be omitted from a work dealing with the
earth colours, because, in former times, it was prepared exclusively
from the mineral malachite. Owing to the fact that artificial malachite
green is one of the cheapest of colours, the troublesome work involved
in the mechanical preparation of the native pigment has been almost
entirely abandoned, and the malachite itself is now utilised to greater
advantage as a source of copper.
Malachite green (or mountain green) is found in nearly every case where
copper ores exist, and is still--though very rarely indeed--prepared,
in a few places, from the mineral, the dark-coloured lumps being picked
out because the lighter-coloured ones would furnish much too pale a
colour.
Public-domain text, read in full here on John Shaqi.
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