The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
On account of the large quantity of mechanically associated water,
freshly dug green earth is greasy in character, like wet clay. In
partial drying, most of this water evaporates, the mass becoming
earthy and adherent to the tongue. Sometimes the colour is an ugly
brownish-green, owing to the presence of a considerable amount of
ferric oxide formed as the result of changes set up by exposing the
mineral to the air. Ferrous oxide is a very unstable compound, having
an energetic tendency to combine with more oxygen and thus undergo
transformation into ferric oxide; so that when green earth is left in
the air for a long time, a considerable proportion of its ferrous oxide
is oxidised to ferric oxide, the mass thereby assuming the brown tone
in question.
Such an unsightly product can, however, be converted, by simple
treatment, into one of very bright and handsome appearance; and it is
this possibility that first enabled green earth to attain importance as
a painters’ colour. Formerly it was only used as a material for common
work, being added to whitewash or employed for indoor paints.
When the crude green earth is treated with very diluted hydrochloric
acid, the compound of ferrous oxide and silica is left intact, but most
of the extraneous admixtures are removed. Ferric oxide, in particular,
passes into solution, and the calcium carbonate largely present in
some kinds of green earth is also dissolved. After prolonged contact
with the crude earth, the acid liquor takes on a brownish coloration
from the dissolved ferric oxide. Since the presence of iron salts
has no influence on the purification of the green earth, the most
impure, highly ferruginous hydrochloric acid can be used, and the
liquor can afterwards be employed in the preparation of artificial
ochre by leaving it in prolonged contact with any strongly ferruginous
mineral, such as brown ironstone, which neutralises the surplus acid.
This liquor is then precipitated by lime, alkali, etc., the resulting
deposit consisting mainly of ferric hydroxide, the further treatment of
which is conducted exactly as described in dealing with the preparation
of artificial ochre.
The treatment of the crude earth is best carried on in the same vessels
as are to be used in the subsequent levigation process. After the acid
liquor has been drawn off, the earth is brought into contact with
water, stirred up well, and the water run off, by opening tapholes in
the side of the vessel, into settling-tanks, where it is left until all
the suspended matter has completely subsided.
The colour of green earth can also be toned by the addition of yellow
ochre, thus producing a range of greens with a yellowish tinge. These
lighter shades, however, are seldom met with in commerce, the trade
judging the quality of green earth more particularly on the depth of
colour.
Public-domain text, read in full here on John Shaqi.
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