The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
In many cases, chalk is found interspersed with nodular masses of
flint, and in some places it also contains great quantities of the
remains of other marine animals, such as sea urchins, the spines of
which occur in such numbers in certain kinds of chalk as to unfit them
entirely for use as a pigment.
The foregoing varieties of calc spar are the most important, and also
occur in large quantities; but, to complete the tale, it is necessary
to mention also a few others which, however, are only found in small
amounts. To these belong, for example, anthracolite, a limestone
stained quite black by coal; the oolithic limestones or roe stones,
which are composed of granules resembling fish roe; muschelkalk,
which is also of fossil character and is almost entirely composed of
mussel shells cemented together with lime; the marls, which consist
of calc spar mixed with varying quantities of clay and consequently
often bear a great resemblance to loam in their properties. A few of
these varieties find extensive employment for certain purposes, some
marls for instance being used for making hydraulic lime, whilst all
modifications of calc spar that are sufficiently pure can be burned for
quick lime.
It has already been stated that the mineral arragonite is identical,
chemically, with calc spar, since both consist of calcium carbonate,
but differ in their crystalline habit. Thus, whereas the crystals of
calc spar belong to the rhombohedral or hexagonal system, those of
arragonite are always rhombic. This occurrence of one and the same
substance in two different crystalline forms is known as dimorphism,
and calcium carbonate is therefore dimorphous. Whether calcium
carbonate assumes the form of calcite or arragonite depends entirely on
physical causes. When the deposition of the carbonate takes place from
a cold solution the shape of the crystals is always one belonging to
the hexagonal or rhombohedral system; but when it is from hot solution,
rhombic crystals are invariably formed, calc spar resulting in the
former case and arragonite in the latter.
These different methods of formation which can be carried out in the
laboratory by producing the requisite conditions, occur on the large
scale in many parts of the world. Wherever a hot spring comes to the
surface, containing considerable amounts of lime in solution, this
separates out in the form of arragonite, which received its name from
the circumstance that specially handsome crystals of this mineral are
found in Arragon.
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