The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
When carbonate of lime, _i. e._ native limestone, is exposed to strong
heat it parts with carbon dioxide and is transformed into burnt or
caustic lime.
CaCO{3} = CaO + CO{2}
Carbonate of lime. Caustic lime. Carbon dioxide.
The limestone is burned either in kilns of very simple construction,
or else in more complicated furnaces in which a continuous process is
maintained. The ordinary limekiln, which can be found in many parts of
the country, consists merely of four walls, with a door in the front
one for the introduction of the fuel. Kilns of this kind are usually
set up in the vicinity of the limestone deposits, and are abandoned
when they get worn out.
The limestone is broken to lumps of fairly even size, about as large
as a man’s head, and these are piled up in a domed heap in the kiln,
sufficient space being left between the lumps for the passage of the
flame. A fire is then lighted under the pile, pine wood being mostly
used for this purpose on account of its high content of resin, which
gives a very strong flame. The fire is kept up until the top of the
pile has become white hot, and only a blue, smokeless flame is visible.
The appearance of this denotes that the burning is ended, the fire
being then allowed to die out and the lumps left until cool enough to
be taken out of the kiln.
This operation is performed with great care, particular importance
being attached to preserving the lumps as intact as possible and
preventing the formation of dust, which is of little value. The lime
made in this way is endowed with properties that render it valuable
for the purposes of the colour-manufacturer; but, on the other hand,
possesses certain disadvantages.
Owing to the use of wood as fuel, the caustic lime obtained in this
way is usually a very pure white, because the burning is continued
until the whole mass is glowing and the firewood has been completely
consumed. If this is not the case, the burnt lime is greyish in colour,
from the finely divided particles of carbon, which, of course, spoils
the lime for colour-making. The defects existing in lime burned in the
above type of kiln originate in the irregular character of the product.
It will be evident that the limestone lumps that are nearest the fire
will be far more strongly heated than those in the upper part of the
dome; and when calcined lime is kept incandescent for a long time, it
becomes so compact in texture that it quenches with great difficulty
when brought in contact with water. This condition is known as “dead
burnt,” and such lime is of little value.
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