The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The lumps at the top of the pile are least exposed to the heat, and
very often still contain carbonate, as is shown by the effervescence
produced on treatment with an acid. Such lime is imperfectly burnt,
and the lumps frequently still exhibit the crystalline structure of
limestone when broken. They quench rapidly, but when mixed with a
little extra water, the mass is no longer of the buttery consistency
typical of caustic lime, but contains gritty portions consisting of
unaltered limestone.
Owing to the defects of dead burning on the one hand and insufficient
calcining on the other, colour-makers now prefer lime that has been
burned in continuous kilns, because, when properly made, such lime is
very uniform in character, and is also cheaper than that burned with
such an expensive fuel as wood. In consequence of the greater capacity
of the continuous kiln, and the more uniform character of the product,
the old-fashioned kilns are more and more falling into disuse.
The arrangement of the continuous kiln is very simple. The kiln
consists of a fairly high shaft, open at the top, and provided at the
bottom with a small hole for the removal of the burnt lime. A coal fire
is lighted, and as soon as the kiln is heated up, alternate layers of
limestone and sufficient coal for burning it are introduced. The burnt
lime sinks to the bottom of the shaft and is pulled out, with iron
hooks, from time to time.
Given the right proportions of coal and limestone, the lime made in
these kilns is burnt to just the right degree, and is excellent for
builders’ use. In many cases, however, it is less valuable to the
colour-maker, and in some quite useless. For example, when the coal
is not completely consumed, carbon, even though only a very small
quantity, is deposited on the lime, and the burnt lime, instead of
being a brilliant white, as it should be, is grey; and colour made
therefrom is also greyish white and will spoil the shade of other
colours with which it is mixed.
The chemical composition of the original limestone also has an
influence on the character of the burnt lime. Limestone consisting
entirely of carbon dioxide and lime is so rare that sufficient is never
available for making burnt lime on a large scale. Even the purest
limestone found native in large quantities--namely marble--is not pure
carbonate of lime, but contains a certain proportion of extraneous
substances. At the same time it is too expensive to use for technical
purposes.
The ordinary impurities present in limestone are ferrous oxide, ferric
oxide, magnesia and organic matter. The presence of ferrous oxide can
usually be detected by the greenish tinge of the raw limestone, and
the reddish cast of the burnt product. Ferric oxide is revealed by its
reddish colour, in both the limestone and burnt lime.
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