The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
As an example of this, mention may be made of iron oxide, which occurs
in Nature in the form of various minerals which can be made into
pigments by mechanical treatment. In many cases, this treatment has
already been carried out by Nature, and deposits of iron oxide are
found in which the material has only to be incorporated with a vehicle
to make it fit for immediate use as a painters’ colour.
Moreover, the same oxide is obtained, in large quantities, as a
by-product of the treatment of other minerals. From the point of view
of chemical composition, this by-product is of very low value, by
reason of the large supplies of native oxide available. By means of
a very simple chemical treatment, however, this by-product oxide can
be considerably improved in commercial value, being, in many cases,
convertible, by merely heating it to certain temperatures, into a
variety of colours which sell at remunerative prices.
Consequently, in view of the present condition of the chemical
industry, the term “earth colours” can be enlarged to include a number
of waste products which fetch good prices as colours, though otherwise
practically valueless in themselves.
The number of earth pigments is very large, and comprises
representatives of all the principal colours. For painting purposes,
few pigments beyond the earth colours were known to the ancients;
and most of the colours in the paintings which have come down to us
from antiquity are pure earth pigments, thus affording proof of their
great durability, having retained their freshness unimpaired for
hundreds--and some for thousands--of years.
The earth colours might be divided into such as occur ready-formed
in Nature, and require only mechanical preparation, and which either
require special treatment (_e. g._ calcining), or are artificial
products (like the iron oxide mentioned above). Since, however, such
a classification would not advantage our knowledge of the nature of
this class of colours, it appears useless and superfluous, and we will
therefore simply confine ourselves to arranging the earth pigments
according to their colour--white, yellow, red, etc.
Adopting this classification, the following minerals and chemical
products may be considered as earth colours:--
_White._--These include the varieties of calcium carbonate, such as
chalk, marble, precipitated chalk, calcium phosphate, calcium sulphate
(in the form of gypsum, alabaster, muriacite and the precipitated
gypsum produced as a by-product in many chemical works), heavy spar,
the different varieties of clay, and magnesia.
_Yellow._--This group comprises ferric hydroxide (hydrated oxide of
iron) in the form of the various minerals known as ochre; all the
preparations chiefly composed of this hydroxide, and all those prepared
by artificial means. A very important member of this group is orpiment;
the other arsenical compounds frequently met with native, being
however, on account of their poisonous properties, no longer used as
pigments.
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