The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
A fundamental condition for the preparation of a good Vienna white is
the employment of pure raw material, which must be free from ferric
oxide or earthy impurities, and fully burned. An excellent material
for this purpose is calcined mussel shells, which furnish a loose,
and at the same time very pure, lime, and are very largely used for
lime-burning in places such as Holland, where they are available in
large quantities.
Vienna white is not much used as a paint colour, owing to its powerful
alkaline properties which have a destructive effect on many colours.
It is, however, largely employed as a polishing agent, for which
purpose it is powdered and is put on the market--mostly in bottles--as
Vienna lime. Its very handsome white colour and low price render it
particularly suitable for coarse painting, for example as a prime
coating for painted interior walls. To guard against the danger of
the painted decoration being destroyed by the alkaline nature of the
white, it is advisable to coat the dried ground with alum solution, the
alumina of which combines with the lime to form an insoluble compound
to which organic colours adhere well. The sulphuric acid also enters
into combination with the lime, the resulting gypsum having no effect
on the paints subsequently applied.
CHALK
The name chalk is used for a number of commercial substances which
differ considerably in both the mineralogical and chemical sense.
French chalk, for instance, is a mineral belonging to the steatite
group and, apart from its name, has nothing in common with true chalk,
except the white colour, and even this differs altogether from that of
chalk properly so called. It is therefore necessary, in the interests
of proper nomenclature, to differentiate the various kinds of chalk,
commencing with the mineral known by that name to the chemist and
mineralogist.
In chemical composition, true chalk is calcium carbonate, but of a
fossil character, for if chalk dust be examined under a high-power
microscope, it will be seen to consist of the shells of minute animals,
and is therefore to be regarded as fossil. The organic matter of the
animals has long disappeared, leaving the inorganic material, a very
pure calcium carbonate, behind.
[Illustration: FIG. 27.]
Such progress has been made that the zoological status of the animals
which inhabited the shells--many thousands of which are present in a
lump of chalk--has been identified; and it is known that these animals
were of marine type. Fig. 27 shows the appearance of the animal remains
in Meudon chalk when highly magnified, the upper half being viewed by
transmitted light and the lower by reflected light.
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