The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The chief requirement exacted of a good quality chalk is a handsome
white colour; and this depends entirely on the quality of the raw
material, not on the method of preparation. It is known that a
substance quite devoid of colour will furnish a perfectly white powder,
because the colourless particles reflect the light in all directions
without breaking it up into its constituent yellow, red and blue rays.
Chalk, too, is in reality a colourless substance, and reflects light
with greater uniformity in proportion as the fineness of the particles
increases. Consequently, when one has a chalk that is not perfectly
white, it can, nevertheless, be made to furnish a very handsome product
by bestowing great care on grinding and levigation. Properly prepared
chalk should be as fine as the finest flour.
When the colour of the best grades of chalk are compared with what may
be termed pure white--such as that of white lead, zinc white, permanent
white--a skilled eye will always detect a greyish or yellowish tinge in
the former, even if obtained from the whitest Carrara marble.
The grey tinge is due to the presence of organic matter, which cannot
be eliminated by any known means, but which can be shown to exist by
the fact that when such chalk is heated to incandescence in the air
for a short time, the resulting burnt lime is pure white, the organic
matter having been burned off. A yellow tinge is caused by minute
traces of ferric oxide, which--as also ferrous oxide--almost invariably
accompanies calcium carbonate; and limestone free from determinable
quantities of these oxides is of rare occurrence. Ferrous oxide does
not reveal its presence in limestone unless in large proportion, its
pale green colour being of low tinctorial power, whereas ferric oxide,
which is a very strong colouring agent, can be more readily detected.
To those who are engaged in the manufacture of white earth colours,
however, it is quite immaterial whether a limestone or chalk contains
ferrous oxide, because that oxide quickly changes into ferric oxide in
the finely divided product, and a chalk which was originally pure white
will become decidedly yellow in a short time.
Fortunately, such a yellow-tinged product can be rendered perfectly
white by simple means and at small cost, all that is necessary being to
add a suitable quantity of a blue colouring matter. When this has been
done, the chalk will seem pure white to even the most skilled eye.
This result of adding a blue pigment is based on the well-known
physical fact that certain kinds of coloured light produce white
light when combined, the colours that give this effect being termed
“complementary.” A pure blue is complementary to a yellow with a
reddish cast--_e. g._ ferric oxide--and therefore a chalk that is
tinged yellow by a small quantity of ferric oxide can be changed into
a seemingly pure white substance by the addition of a blue pigment.
Public-domain text, read in full here on John Shaqi.
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