The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The only pigments of use in this connection to the colour-maker are
such as have very intensive colouring power and at the same time
are low enough in price. Such substances are ultramarine, smalt and
coal-tar dyes. Smalt is the best because its colour is unalterable.
In point of chemical composition, this substance is a very hard glass
coloured blue by cobaltous oxide. For improving the colour of chalk
or any other white, the smalt must be in an extreme state of fine
division, and levigated to an impalpable powder. Ultramarine can be
used for the same purpose, but is not so permanent.
To ascertain the correct proportion of blue pigment, it is advisable
to make a systematic experiment, which is easily performed. Exactly
90 parts of the chalk in question are triturated with 10 parts of
blue pigment in a mortar until the entire mass has become a perfectly
uniform pale blue powder, which contains 10% of the blue ingredient.
Several samples, each representing one hundred parts of the white
pigment to be corrected are carefully weighed out, 1 part of the blue
powder being added to the first sample, 2 parts to the second, 3 to the
third, and so on, and the mixtures are compared with a standard white
substance, such as best white lead or zinc white, to see which most
nearly approaches the standard colour. It is then easy to calculate
how much of the blue requires to be added to 100 or 1000 lb. of the
material to be corrected.
The correction can be effected in several ways; for instance, by
grinding the blue pigment directly with the bulk, by adding it at the
levigation stage, or mixing it with the dry, finished product. The
first two methods are attended with certain drawbacks which render
it difficult to obtain a perfectly uniform product, owing to the
specific gravity of the blue pigments being higher than that of the
whites. Consequently, when the two are mixed in presence of water--as
is always the case in grinding and levigation--the heavier blue
pigment settles down more quickly, and several strata can be clearly
distinguished in the sediment. The upper layers will still have a
decided yellow tinge--the proportion of blue being too small for proper
correction--whilst the next in order will be pure white--accurately
corrected--and those at the very bottom will be decidedly blue, because
they contain the largest proportion of the blue substance.
The most satisfactory results are obtained by dry mixing; and this can
be successfully practised when the colour-maker has a cheap source of
power (such as water power) available. Where, however, costly power
plant has to be provided, only the finest grades of white pigments can
be improved in this way, the expense of labour being too high for cheap
materials.
Public-domain text, read in full here on John Shaqi.
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