The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
This deposit is stirred up again at intervals with the liquid for
several days. When ferric oxide is present, the colour of the deposit
will gradually change to a yellowish brown, through the precipitation
of ferric hydroxide by the chalk; and in this way the final traces of
iron can be removed.
The liquid is then carefully drawn off, without disturbing the
sediment, and the soda solution is run in so long as a precipitate of
calcium carbonate continues to form. The completion of the reaction
can be ascertained by pouring a small quantity of the liquid into a
tall, narrow glass, leaving it to clarify, adding a little more soda
solution and observing whether any further precipitate is produced.
On the other hand, it may be that an excess of soda has already been
added in the precipitating tank; and this can be determined by testing
a sample with turmeric paper--blotting-paper soaked in a solution
of the colouring-matter of turmeric root--which is turned brown by
alkaline reagents. Even in very dilute solution, soda will give this
colour change, and the test is therefore very accurate. The complete
precipitation of the lime in the solution can be ascertained by passing
a small quantity through blotting-paper and treating it with a little
acid potassium oxalate solution, which, if lime be present, will at
once produce a strong crystalline precipitate of calcium oxalate, which
is only very sparingly soluble in water. If the oxalate gives merely
a slight turbidity, the residual amount of lime is so small that the
process may be regarded as complete.
Since carbonate of soda is usually much dearer than the lime-salt
liquor, it is preferable to leave a small quantity of the lime
unprecipitated. Given sufficient care in effecting the precipitation,
and especially when fairly strong solutions are used, a brilliant white
precipitate of calcium carbonate is obtained, which is in such a finely
divided state that the minute constituent crystals can only be detected
under a high magnifying power.
This precipitated chalk being already in an extremely fine condition
needs no further preparation, and, when washed, is ready for immediate
use, forming a handsome pigment with excellent covering power.
When precipitation is ended, the deposit is allowed to settle down,
and the clear supernatant liquid is carefully drawn off so as not to
disturb the delicate sediment, which is then stirred up thoroughly with
clean water, left to subside, washed again, and then spread out to dry
on cloths which are suspended by the four sides. The surplus water
drains away and the residue gradually assumes the consistency of paste,
in which condition it can easily be moulded to any desired shape. If
left long enough to dry completely, it forms a very delicate powder,
furnishing a pigment of excellent quality.
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