The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
If this precipitated chalk be moulded into prisms for sale, the blocks
are laid on one of their broad sides until firm enough to turn over
on to one of the narrow faces, slabs of gypsum being used as the
supporting material, in order to ensure uniform drying. The gypsum
absorbs water with avidity and thus dries the prisms evenly.
A defect of these prisms is their great fragility; but their strength
may be improved by mixing a little very weak solution of dextrin to
the mass after the last washing-water has been completely removed. In
drying, the dextrin binds the material of the prisms sufficiently to
keep them from breaking except under the influence of a fair degree of
force.
CALCAREOUS MARL
As already mentioned, calcium carbonate rarely occurs in a perfectly
pure condition in Nature; and chalk, also, is frequently contaminated
by other minerals. A variety of limestone occurring as extensive
deposits in many places is that in which calcium carbonate is
associated with clay. Sometimes the clay predominates, and the mineral
is then known as marl, being really a clay contaminated with chalk. If,
on the other hand, the chalk forms the chief constituent, the mineral
is termed calcareous marl.
Calcareous marls are used in much the same way as limestone, some
modification, however, being necessitated by the presence of the clay.
Although limestone containing a certain amount of clay can be burned
in the kiln, it yields an inferior lime that is of little use to the
builder owing to its low binding power. Marl of a certain composition
finds an important application in the manufacture of hydraulic lime or
cement.
The only kind of marl suitable for pigment is that containing clay
with very little colour; and this is of somewhat rare occurrence,
because most marls contain sufficient ferric oxide to give them a
yellow shade. Marl that is fairly free from ferric oxide, however, can
very well be used as pigment; and many white pigments sold as “chalk”
are really finely ground marl. In accordance with the general practice,
in the colour industry, of giving colours a great variety of names, and
suppressing the real names, which, so far as the artificially prepared
colours are concerned, should bear some reference to their chemical
composition, numerous white earth colours bear fancy names, though
really consisting of chalk, lime (generally marl), or white clay.
In France, where both chalk and clay are of frequent occurrence--the
soil of Champagne, for instance, being all chalky--the manufacture of
the white earth colours is extensively practised, and a large number
are put on the market, usually named after the place of origin, and
consisting of either calcium carbonate or marl.
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