The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The employment of barytes in the colour industry is often regarded as
adulteration, which, however, it is not when the case is considered
from the right point of view. For instance, the only preparation which
can properly be termed white lead consists of basic lead carbonate.
This, when pure, is a rather expensive pigment, whereas, for certain
purposes, the consumer requires a product that can be obtained at a low
price. In order to satisfy this demand, the only course open to the
colour-maker is to mix the white lead with a cheap white substance,
which enables him to turn out different grades of white lead, which,
although low in price, are far inferior to the pure article in covering
power. Pure white lead being itself a very heavy substance, the only
bodies suitable as adjuncts are such as are also of high specific
gravity; and of all the cheap pigments known, heavy spar is the only
one endowed with this property. Consequently, this substance is
extensively used in making the cheaper grades of white lead and the
pale kinds of chrome yellow.
The only cases in which the addition of heavy spar to a colour can be
regarded as an intentional fraud on the consumer is when he is sold,
as pure white lead, chrome yellow, etc., a product really composed
of a mixture of such colour and barytes. Moreover, the presence of
barytes in white lead can be easily detected by a simple examination,
pure white lead readily dissolving, with considerable effervescence,
in strong nitric or acetic acid, whereas barytes is insoluble in all
acids, and therefore remains, as a heavy white powder, at the bottom
of the vessel. In this way both the presence and amount of barytes
contained in a sample of white lead or chrome yellow can easily be
ascertained.
The preparation of barytes for the purposes of the colour-maker is
entirely a mechanical operation. The barytes, which though fairly hard
is easily reduced, is crushed with stamps, ground in a mill and finally
levigated, it being impossible to obtain a sufficiently fine powder
even by repeated grinding.
Native barytes must not be confounded with the artificial barium
sulphate sold as permanent white or blanc fixe, which is an extremely
finely divided barium sulphate obtained by precipitating a solution
of a barium salt with sulphuric acid or a soluble sulphate, and is
a painters’ colour that is highly prized for certain purposes. Both
the native sulphate and the artificial variety have the property
of remaining completely unaltered by exposure to air, and they can
therefore be mixed with any kind of pigment without fear of the colour
deteriorating.
As a rule, barytes is first roughly crushed in edge-runner mills or
stamps, and then ground to the extreme degree of fineness obtainable in
ordinary mills. Even with the greatest care, however, it is impossible
by this means to obtain sufficient fineness of division for mixing with
fine colours, the only way in which this can be accomplished being by
levigation.
Public-domain text, read in full here on John Shaqi.
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