The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
Given a fairly pure white barytes to begin with, levigation furnishes a
handsome white pigment that can be mixed with colours of any kind; but
when used by itself in association with oil or varnish, its covering
power is very low and the colour never perfectly white. Native barytes
is therefore unsuitable, as such, for paint.
Varieties that are not pure white are sometimes corrected with
ultramarine, added in the grinding-mill. If the yellow tinge is due
to iron compounds, this can often be remedied by treating the finely
ground material with hydrochloric acid, which dissolves them out, this
treatment being followed by a thorough washing with pure water.
As already mentioned, white lead is most frequently mixed with barytes,
this being usually added when the white lead is being ground, by
feeding the two materials to the mill and grinding them together.
The crudeness of mechanical methods of reduction is clearly
exemplified by comparing the most carefully ground and levigated
barytes with that obtained by artificial means. The permanent white
largely used in the production of wall-paper, and quite unalterable
in air, is, chemically speaking, identical with native barytes, viz.
barium sulphate. The two also seem to be identical in crystalline
habit, as is usual in the case of one and the same mineral, whether
native or prepared by artificial means. Artificial barytes is obtained
by treating a soluble salt of barium with sulphuric acid, or a solution
of sodium sulphate (Glauber salt), so long as a precipitate continues
to form.
This precipitate is barium sulphate, which subsides completely on
account of its extreme insolubility, this being greater than that of
any other salt known. The rapid rate of deposition results in the
formation of extremely small crystals, which, being colourless and
reflecting the light completely, appear to be perfectly white. Even
when permanent white is applied in very thin layers to any surface, its
covering power is very considerable, by reason of the extremely fine
subdivision of the material.
This behaviour of artificial barytes in comparison with that of the
natural product, affords an important hint in connection with the
preparation of earth colours, namely, that in order to obtain products
of specially good quality, the endeavour should be to reduce the raw
materials to the finest condition possible. This result is accomplished
most securely by bestowing the greatest care on grinding and
levigation; and it is therefore highly important that the manufacturer
should select, from the various apparatus used in reducing the
materials, those that are best adapted for the purpose.
CARBONATE OF MAGNESIA
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