The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
Occasionally, the ferric hydroxide is associated with a certain
proportion of clay, and as this increases, the ochre passes over into
ferruginous clay. This class can also be used as pigment, in certain
circumstances, that is to say when it is sufficiently rich in ferric
oxide to furnish a deep red mass on calcination. When, however, the
proportion of ferric oxide is low, its pigmentary power is no longer
sufficient, and the clay has not the requisite beauty of colour. The
ordinary earth used for making tiles is an example of this class, its
colour in the raw state being an ugly brownish-yellow, but turning a
dull “brick” red when fired.
In some deposits the ferric oxide is accompanied by lime. Unless the
latter exceeds a certain proportion, such ochres, too, are suitable as
pigments, the lime being easily removed by simple levigation; but when
the amount of lime is high, it is difficult to obtain certain highly
coloured shades of ochre from such material. These shades entail the
calcination of the ochre, and the temperature required is oftentimes
insufficient to transform the lime into the caustic state. Moreover,
the presence of caustic lime would be a drawback in some cases, it
being then impossible to mix the ochre with other colours without
endangering the shade through the action of the lime on these latter.
The following analyses will show the percentage composition of ochres
from various deposits:
Ochre from--
+-------------+---------+----------+--------------+
| | Comoal | Vierzen. | St. Georges. |
| |(Savoy). | | |
+-------------+---------+----------+--------------+
|Ferric oxide | 19 | 23·5 | 25 |
|Lime | 2 | -- | -- |
|Alumina | 20 | 69·5 | 70 |
|Magnesia | 1 | 69·5 | 70 |
|Silica | 44 | 69·5 | 70 |
|Water | 7 | 7 | 5 |
+-------------+---------+----------+--------------+
In the majority of cases the mineralogical characteristics of an ochre
enable conclusions to be formed as to its suitability as pigment. Good
ochre is more or less yellow to dark brown in colour, and can easily
be crushed between the fingers to a soft, fine powder which feels like
powdered steatite and does not produce a sensation of grittiness, this
latter indicating the presence of fine grains of sand in the ferric
oxide. The behaviour of the ochre in presence of water is specially
important. If it adheres firmly to the tongue, and forms a fairly
plastic paste when mixed with a little water, the mineral contains a
large percentage of ferric oxide, and as a rule will yield ochre of
good colour.
In general it may be said that the value of an ochre varies directly
with its content of ferric hydroxide or oxide, because when this is
large the ochre will furnish a wide range of colours under suitable
treatment.
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