The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
In addition to the foregoing, which have ferric oxide for their
pigmentary principle, is the native mercury sulphide, occurring, as
scarlet, crystalline masses, under the name of cinnabar (vermilion).
The only reason for including natural vermilion with the earth colours
is to make the list complete, the largest proportion of this pigment
being prepared by artificial methods. The product sold as “Chinese”
vermilion may, in former times, have really been introduced from
China into Europe, and prepared there by grinding and levigating the
best-coloured lumps of the natural cinnabar; but, at the present
time, all the vermilion made--in Europe at least--is from sulphur and
mercury, by artificial processes, and the name Chinese vermilion is
merely retained to designate a particularly fine grade.
On the basis of occurrence and chemical properties, the red earths
can be classified into several groups. The first comprises natural
products requiring only mechanical preparation, such as the minerals
known as hematite, micaceous iron ore, Elbaite, etc., and the special
modification of red ironstone termed raddle. All these minerals consist
almost entirely of ferric oxide in a pure state. The mineral, bole (red
chalk, terra sigillata, Lemnos earth), is chemically allied to the
ochres, being, like them, composed of alumina, frequently accompanied
by lime and small quantities of magnesia, but differing in that ferric
oxide is always present in bole, whereas the ochres always contain
ferric hydroxide.
The second group consists of the artificial reds obtained by burning
or calcining raw materials, whose ferric hydroxide is more or less
transformed by heat into ferric oxide, such as vitriol ochre, pit ochre
and alum sludge.
Of late years the artificial earth colours have attained a high degree
of importance. They are obtained in large quantities in the manufacture
of sulphuric acid from green vitriol. Formerly, it is true, they were
also used as pigments under the name of caput mortuum or colcothar, but
were not held in much esteem; and it is only within recent times that
it has been discovered that these inferior by-products can be converted
into very handsome and brilliant colours, which now form important
articles of commerce.
BOLE
Bole, Lemnos earth, terra sigillata, etc., is, for the most part, a
product of the decomposition of highly ferruginous minerals, and
occurs, in the form of lumps, having a conchoidal fracture, in pockets
or detritus. The lumps have a sp. gr. of 2·2–2·5, are Isabella brown to
dark brown in colour, and give a slightly greasy-looking streak. There
are two distinct varieties of bole: the one adhering firmly to the
tongue, whilst the other lacks this property and, when placed in water,
crumbles down to powder in emitting a peculiar noise.
Public-domain text, read in full here on John Shaqi.
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