The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The composition of the boles varies, but all of them may be regarded
as alumino ferric silicates combined with water. Most of the specimens
examined from different deposits contain 24–25% of water, 41–42% of
silica, and 20–25% of alumina, the remainder consisting of ferric oxide
with small traces of manganese oxide.
Some varieties, however, are exceptional and contain only 30–31% of
silica and 17–21% of water, _e. g._ those from Orawitza and Sinope.
Lemnos earth, the true terra sigillata, is mostly silica (66%) with 8%
of water, and contains a smaller percentage of ferric oxide than the
others. It is also of a distinct colour, lighter than the true boles
and having a greyish or yellowish tinge.
The behaviour of the different kinds on burning is just as diverse as
their chemical composition. Whilst some kinds are infusible at even the
highest temperatures, and merely change into hard, red masses; others,
again, fuse at a moderate heat. This difference is due to chemical
composition, those high in silica being generally less refractory than
those in which alumina preponderates.
In order to render the boles suitable for painting, they are put
through a somewhat different treatment than the other earth colours.
The freshly dug material is first sorted, the uniformly coloured lumps
of fine texture being set apart and suffused with water, with which
they form a pasty mass of low plasticity, which is kneaded by hand
to make it homogeneous, and is then stirred up with more water. When
the lumps have distributed in the water, the latter is drawn off into
a second tub, and the residue is stirred up with fresh water, the
treatment being repeated until the effluent no longer shows any signs
of colour.
The liquid in which the finely divided bole is suspended is left to
settle, and the bole subsides as a fine powder, which is dried to the
condition of paste, pressed into moulds and dried completely.
Owing to its low content of ferric oxide, the colour of bole is not
particularly bright, but is very permanent--a property equally shared
by all the other ferric oxide pigments.
NATIVE FERRIC OXIDE AS A PIGMENT
In nature, ferric oxide forms extensive deposits, which, by reason of
the light red colour characteristic of certain varieties of ferric
oxide, are largely employed in painting. These colours may be classed
among the oldest known to mankind, ferric oxide pigments having been
used frequently in the most ancient paintings.
The most important varieties of ferric oxide for our purpose are: iron
glance, with its modifications, micaceous iron ore and frothy hematite;
red hematite, and raddle.
IRON GLANCE
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