The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
Although the number of green-coloured minerals is large, but few
of them are suitable for painters’ colours, because they occur so
rarely in Nature that their employment for this purpose is out of the
question, more especially since a very large number of green pigments
can be obtained by artificial means. The most important of the earth
colours in this category are Celadon green, or green earth, and
malachite green--the latter, however, less so, because the substance of
which it is composed can be prepared artificially.
GREEN EARTH, OR CELADON GREEN
This mineral is of a peculiar green colour, and the name “Celadon
green” has been universally adopted in the nomenclature of colour
shades. Green earth occurs native in many places, being the
decomposition product of an extensively distributed mineral, augite,
crystals of which are found in many of the deposits. The green earth of
Monte Valdo, on Lake Garda (Upper Italy) has been used for a very long
time as a pigment. It is chiefly prepared in Verona for distribution
in commerce, and from this circumstance has acquired the name “Verona
green,” or “Verona earth.” The earth is also found in Cyprus and
Bohemia, where it frequently occurs as the decomposition product of
basaltic tuff. However, whether obtained from Monte Valdo or elsewhere,
the product is always placed on the market as Verona earth.
Native green earth is always tough, mostly occurring in amygdalous
lumps, but occasionally in the crystalline form of augite. It has
a fine-grained fracture, a hardness between 1 and 2, and a sp. gr.
between 2·8 and 2·9. The colour is not always quite uniform, pure lumps
having the characteristic Celadon green appearance, whilst impure
lumps are olive green to blackish green. In chemical composition it is
chiefly ferrous silicate, and this compound must be regarded as the
actual pigmentary principle of green earth. In addition, it contains
varying quantities of other compounds which influence the depth of
shade of the product.
Verona earth chiefly consists of ferrous oxide in combination with
silica; alumina, magnesia, potash, soda and water being also present.
Analysis shows it to contain: ferrous oxide, 21%; silica, 51%;
magnesia, 6%; potash, 6%; soda, 2%; and water, 7%.
The green earths from Gösen, Atschau and Männelsdorf, near Kaaden
(Bohemia) and the Giant’s Causeway (Ireland) have the following
composition:
+---------------+----------+----------+
| | Kaaden. | Giant’s |
| | | Causeway.|
+---------------+----------+----------+
|Silica | 41 | 56·4 |
|Alumina | 3 | 2·1 |
|Ferrous oxide | 23 | 5·1 |
|Ferric oxide | -- | 14·1 |
|Lime | 8 | -- |
|Magnesia | 2 | 5·9 |
|Potash | 3 | 8·8 |
|Carbon dioxide | 19 | -- |
|Water | -- | 6·8% |
+---------------+----------+----------+
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