The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Other formulæ which are said to yield a good result are as follows:
12 parts of white lead, 3 parts of antimony oxide, 1 part of ammonium
chloride, 1 part of alum. Or: 16 parts of stibnite, 24 parts of lead,
1 part of common salt and 1 part of ammonium chloride. The intimate
mixture of these materials is first gently heated with access of air,
then more strongly, and the mass extracted with water. There are many
other recipes for the preparation of Naples yellow, the majority of
which are distinguished by an apparently arbitrary arrangement of the
materials; for there is no scientific reason. If it were possible to
accurately obtain any desired high temperature in a furnace, the
manufacture of Naples yellow would no longer be a matter of skill, but
the same product could be obtained at every attempt. Since this is not
yet the case, the exact procedure for the preparation of this colour
can only be found by careful experiments.
Naples yellow is, as has been said, a handsome colour, and offers a
great resistance to varied reagents. It is only changed by one of them,
sulphuretted hydrogen, by the prolonged action of which it is turned
completely black.
=Antimony Yellow= is very similar in composition to Naples yellow.
It consists of a mixture of lead antimoniate with the oxides of lead
and bismuth. It is prepared by the process recommended by Meromé by
intimately mixing 3 parts of finely powdered bismuth with 24 parts
of powdered stibnite and 64 parts of saltpetre, melting the mixture
and shaking it whilst molten into water. The brittle mass is finely
powdered, washed and dried, then melted with 128 parts of litharge
and 8 parts of sal ammoniac. The mass obtained has a fine pale yellow
colour; when powdered it is antimony yellow. This pigment has almost
fallen into disuse because of its instability and the high price of
bismuth.
=Calcium Chrome Yellow.=—Calcium forms a yellow pigment with chromic
acid, which, although far surpassed by the lead chromes in fineness of
shade, has the advantage over them of greater stability and cheapness.
For purposes for which cheap and at the same time permanent colours
are required calcium chrome yellow can be recommended. It is most
simply prepared from potassium chromate and calcium chloride, which,
as a by-product of many chemical operations, is obtainable at very low
prices. The deepest pigment is obtained when the precipitation is done
with a boiling solution of the chromate. Calcium chromate, in addition
to its use alone, may be employed instead of white pigments to produce
pale shades from deep lead chromes. This addition should not be carried
to a great extent or the chrome will be made too light, since calcium
chromate has a much lower specific gravity than lead chromate.
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