The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
A simpler method is to dissolve equal parts of lead nitrate and
potassium iodide separately, each in 20 parts of hot water, to mix the
solutions and cool quickly, when lead iodide separates in very small
crystals. When pure lead iodide is melted in the absence of air, and
the fused mass powdered, a product of yet finer colour is formed. It
is necessary to completely imbed the crucible in which the fusion is
performed in the fire. The action of air on the melted mass would
produce a basic iodide. The fine golden yellow colour of lead iodide
adapts it especially for the production of gold bronzes on wall papers
and fabrics.
=Mars Yellow=, which is generally reckoned among the best artists’
colours, is usually a mixture of ferric oxide and calcium sulphate
or alumina. The pigment is prepared by mixing a solution of ferrous
sulphate with milk of lime, when ferrous oxide is precipitated, which
becomes yellowish brown on exposure to air, in consequence of the
oxidation of the ferrous oxide. By heating the precipitate, according
to the temperature different shades are obtained, varying between
yellow and red. In addition to Mars yellow, Mars orange and Mars red
are found in commerce.
The manufacture of this pigment is very simple: 1 part of ferrous
sulphate is dissolved in 10 parts of water, and the solution mixed with
milk of lime made from 1 part of quicklime and 40 parts of water. If it
is desired to produce a darker shade, and especially a product to be
afterwards converted into Mars orange, the amount of ferrous sulphate
is increased to 2 parts. When the mixture has been made, it must be
stirred for a long time, in order that the reacting substances may come
thoroughly into contact. The precipitate, which at first is greenish
grey, soon acquires by the action of the air the colour of ferric
hydroxide, which becomes deeper on drying.
When dried and finely ground Mars yellow is heated in thin layers, it
changes to dark yellow, and finally to orange red, a similar alteration
taking place to that occurring when ferric hydroxide itself is heated.
A Mars yellow of a deeper shade, consisting of a mixture of ferric
hydroxide and alumina, is obtained by precipitating with caustic soda
a solution of ferrous sulphate and alum. The sodium sulphate which is
formed at the same time must be removed as completely as possible by
washing with boiling water.
By calcining Mars yellow for a long time at a high temperature, Mars
brown is produced, a fine brown pigment. The value of Mars yellow and
the pigments obtained from it lies not only in their fine shade, but in
their permanence, which distinguishes the majority of the iron colours.
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