The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Siderin Yellow.=—This not very handsome yellow consists of ferric
chromate; it is obtained by adding a neutral solution of ferric
chloride to a strong boiling solution of potassium bichromate so long
as a precipitate is formed. Siderin yellow is said to be used both
in oil and water, and to be particularly adapted for use in sodium
silicate paints, since in the course of time it forms a stony mass with
that substance.
The low price of iron salts would make it desirable to employ chromates
of iron, but it appears to be difficult to obtain a compound of
constant composition. In experiments with this object the author did
not succeed in obtaining products of the same shade. Others have
probably been equally unsuccessful, for siderin yellow has never been
used in quantity, as it would have been were there no difficulties in
the way of its preparation.
=Aureolin= is a double nitrite of cobalt and potassium, Co(NO₂)₂.3
KNO₂. This pigment is prepared by adding excess of potassium nitrite to
a solution of cobalt nitrate acidified with acetic acid. As the liquid
cools, a deep lemon yellow crystalline powder separates, which, when
dry, is known as Indian yellow or aureolin. It is distinguished from
other yellow pigments by being unaffected by sulphuretted hydrogen.
The potassium nitrite required in the preparation of this pigment
is most easily made by melting saltpetre in a thick iron vessel and
stirring in fine iron filings in small quantities as soon as the
saltpetre begins to decompose. The iron glows brightly and burns
to oxide, the saltpetre changes to potassium nitrite. The mass is
dissolved in a little hot water, the solution filtered and cooled,
when most of the undecomposed saltpetre crystallises out, whilst the
nitrite remains in solution. After further evaporation and separation
of another crop of potassium nitrate crystals, the solution can be used
to precipitate the aureolin.
It is advisable to use strong solutions in the precipitation of
aureolin; the finest precipitate is obtained in this way. If dilute
solutions are used, the precipitate forms gradually; it is then coarse
and has little covering power.
According to the method of Hayes, aureolin is prepared by passing into
a solution of cobalt nitrate the vapours produced by pouring nitric
acid over copper and allowing air to enter. Caustic potash is added
to the liquid from time to time. In this way all the cobalt can be
obtained in the form of a yellow precipitate.
=Tungsten Yellow.=—Finely powdered tungsten is introduced in small
quantities into fused potassium carbonate so long as effervescence
occurs. After boiling with water and filtering, calcium tungstate is
precipitated from the filtrate by means of calcium chloride. The moist
precipitate is added to hot dilute nitric acid until the liquid is only
slightly acid, when it is boiled for half an hour and allowed to cool.
The precipitate, after washing with a little water and drying, is a
deep lemon yellow powder.
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