The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Nickel Yellow= consists of nickel phosphate. It is obtained by adding
sodium phosphate to a solution of nickel sulphate or nitrate, and
heating the pale green precipitate to redness. Nickel yellow has a
pleasing shade, and is distinguished by great permanence. Up to the
present it has found little use as an artists’ colour, but on account
of its permanence, which does not distinguish many yellow pigments, its
use is to be recommended.
=Mercury Yellow or Turpeth Mineral= is a basic mercuric sulphate of the
formula Hg₃SO₆. It is obtained by heating 10 parts of mercury with 15
parts of sulphuric acid in a porcelain dish in a good draught, until a
white crystalline mass of neutral mercury sulphate remains. This salt,
HgSO₄, is decomposed in contact with water into free sulphuric acid and
a basic salt of the above composition. The decomposition is effected
by treating the finely powdered neutral sulphate with hot water so
long as the washings are acid, when a handsome lemon yellow substance
remains. The wash waters contain acid mercuric sulphate. They are
allowed to stand with mercuric oxide so long as this is dissolved, and
the solution then used to prepare new quantities of mercury yellow.
Turpeth mineral has a very bright shade and great covering power,
but it has little permanence. Sunlight soon turns it grey, and air
containing sulphuretted hydrogen in a short time turns it quite black,
mercury sulphide being formed.
=Yellow Arsenic Pigments.=—The extremely poisonous character of arsenic
pigments has practically banished these handsome and cheap colours
from use. In many countries their use is justly illegal. The majority
of arsenic pigments have, therefore, merely historic interest. The two
yellow arsenic pigments are found in nature as realgar and orpiment;
though these are not rare minerals, the artificial products were
generally used as pigments, and when they were in common use they were
generally made in metallurgical works, in which minerals containing
arsenic were treated.
Realgar, As₂S₂, has an orange red colour, whilst orpiment, As₂S₃, is a
pure yellow. When these substances were used as pigments they had the
same drawbacks in regard to mixing with other pigments as other sulphur
compounds. King’s yellow is finely powdered natural or artificial
orpiment.
=Lead Arsenite= is a permanent deep yellow, but extremely poisonous. It
can be made by fusing an intimate mixture of 100 parts of white arsenic
with 75 parts of gold litharge, grinding and levigating the mass.
Cadmium yellow, which has still more permanence and is less poisonous,
replaces this pigment.
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