The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The usual process in Holland, especially in the Amsterdam works, is as
follows: The black sulphide is made by heating 270 parts of mercury
with 37·5 parts of sulphur in copper pans—the fire is so regulated that
the temperature is not high enough to ignite the sulphur. If properly
prepared the product has now a pure black colour. It is immediately
finely ground and preserved in earthenware bottles containing only 0·7
kilogramme each. It is sublimed from hemispherical vessels, provided
with iron covers carefully joined to the rim of the sublimation vessel
by a suitable fire-resisting cement. Generally 3 such vessels are
contained in one furnace. The operation is commenced by heating them
until the bottom shows a dark red heat. The temperature should now
be increased to such an extent that, when the contents of one of the
above-mentioned small bottles are poured into the vessel, a small flame
only appears; if on the contrary the contents burn explosively, the
temperature is too high, and further quantities of the black sulphide
must not be added until the vessels have cooled down to a certain
extent. If, on introducing the first quantity of mercuric sulphide, a
flame appears unaccompanied by an explosion, the contents of several of
the bottles may be introduced; the openings through which this addition
is made are immediately closed by a well-fitting iron plate. From time
to time this cover is raised and fresh quantities of mercuric sulphide
added. The operation lasts about 36 hours, when double the quantity of
mercuric sulphide, made from the above mixture of mercury and sulphur,
will have been introduced into the 3 vessels. For the complete success
of the process, the accurate regulation of the temperature to which
the vessels are exposed is particularly important; in practice, the
temperature is judged by the height of the flame which issues on
removing the iron plates: if this reaches to 1 metre the fire is too
fierce, but if the flame is very small the fire must be increased.
Towards the end of the sublimation the mass in the vessels is stirred
about every 15 minutes. As soon as the sublimation is finished the
fire is extinguished. The vessels are broken when completely cold; the
vermilion is then found in the upper portion as a sublimate of fibrous
character. The vermilion made by this process requires simply wet
grinding under ordinary mills and drying to be ready for market.
Public-domain text, read in full here on John Shaqi.
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