The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
In the great mercury works at Idria, in Austria, vermilion is also
made from the black sulphide. The latter is made by mixing 84 parts
of mercury with 16 parts of finely powdered sulphur in rotating
vessels driven by water power, the operation lasting about 3 hours.
This quantity of sulphur is larger than is required to form mercuric
sulphide; experience has shown that the combination takes place more
rapidly when more than the equivalent quantity of sulphur is used.
Heat is developed by the reaction and the temperature of the mixture
rises to over 30° C. The black sulphide is then sublimed in cast-iron
vessels, which are pear-shaped and built 6 together in a furnace; each
holds a charge of 315 kilogrammes of black.
Several periods are distinguished during the heating of the mass in
the sublimation vessels. The operation is commenced by heating 2 of
the vessels first. As soon as the vapours of sulphur, issuing from the
neck of the vessels, take fire with explosion, the fire is made to
heat the adjacent vessels. When the contents of all the vessels have
exploded, the first part of the process known as the “evaporation” is
at an end. Earthenware heads are then placed on the vessels and the
fire is increased until the excess of sulphur present begins to distil;
its vapours take fire in the air with a slight explosion. When this
takes place, earthenware receivers are attached which have only a small
opening for the escape of uncondensed vapours. The sulphur condenses
in these. When sulphur vapours are no longer given off in quantity,
the intermediate period (_stϋckperiode_) is finished and the real
sublimation of the vermilion commences. The fire is now considerably
increased and the sublimed vermilion collects in the cooler parts of
the apparatus. When the sublimation is completely finished, small blue
flames, which quickly vanish, appear at the joints of the apparatus.
The furnace is allowed to get quite cold, when the various parts of
the apparatus are taken apart, the vermilion deposited in the tubes
is carefully removed, so that they may be again used, whilst the
receivers and head are broken, so that the vermilion they contain can
be collected.
The larger pieces form lump vermilion; the fragments of the receivers
are cleaned with a wet brush to collect what adheres. The whole process
of sublimation from the introduction of the black to the end lasts
about 7 hours.
The sublimed vermilion is ground in mills which differ little from
ordinary grinding mills. To prevent the formation of dust, water is
added and the stones are surrounded by wooden casings. The red paste
from the mills, which is now known as vermilion, is then refined.
Public-domain text, read in full here on John Shaqi.
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