The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The refining consists in extracting the excess of sulphur by means of
boiling potash solution; 300 kilogrammes of the ground vermilion are
stirred up with water in a tub, the water is drawn off and the wet mass
brought into an iron pan, in which it is heated with 22·5 kilogrammes
of potash lye for about 10 minutes. According to the composition of
the crude vermilion the lye has a strength of from 10° to 13° B. The
smaller the quantity of sulphur, the weaker is the potash solution; it
is, or was, made in Idria in a very primitive manner, by extracting
wood ashes. For vermilion of a bright red shade potash solution of 10°,
for the dark red of 11°, and for “Chinese vermilion” of 13° is used.
The excess of sulphur, together with a trace of mercuric sulphide,
dissolves in the potash solution; the sulphur chiefly forms potassium
pentasulphide. When the boiling is finished, the vermilion is carefully
washed and dried in dishes placed in a heated furnace. During drying,
the vermilion agglomerates; finally the lumps are broken and sieved.
=Chinese Vermilion= is in similar case to Indian ink. Both substances
are in common use in Europe, they far surpass in quality our own
manufacture, and in neither case do we know the exact method by which
they are made. Genuine Chinese vermilion so far surpasses European in
brightness that it is bought at five or six times the price. It is
said on unauthenticated authority to be made by subliming a mixture
of 4 parts of quicksilver with 1 part of sulphur in earthenware pots
closed by an iron plate, which is kept constantly wet and serves as a
receiver, on which the vermilion deposits. The sublimed masses adhering
to the lid are sorted, ground and repeatedly washed with water.
According to Callum’s description of the manufacture of vermilion at
Hong Kong, mercury and sulphur are heated in a large iron pan, with
continual stirring at about the melting point of sulphur (111° C.),
until the whole has changed to a black mass. After cooling, this is
mixed with water and mercury, the mixture thoroughly stirred, dried,
placed in a hemispherical dish and covered over with broken porcelain.
A similar dish is cemented on the top of the first, and the dishes are
heated for 16 hours; the vermilion adhering to the porcelain fragments
is removed, wet ground and dried.
A vermilion approaching Chinese in beauty is said to be obtained by
mixing ordinary vermilion with 1 per cent. of antimony sulphide and
again subliming the mixture. The dark grey sublimate produces a reddish
brown powder, which is repeatedly boiled with a solution of “liver of
sulphur” (potassium polysulphide), washed with water and digested for
a long time with hydrochloric acid. The author has repeatedly made
vermilion by this process, but could never obtain a product differing
appreciably from the original vermilion.
(b) WET METHODS.
Public-domain text, read in full here on John Shaqi.
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