The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
In order to prepare ferric oxide suitable for an artists’ pigment the
following process may be used: 17 parts of soda are dissolved in 68
parts of water; the solution is boiled in an iron pan, and 10 parts
of crystallised ferrous sulphate are added in small quantities with
continual stirring. The boiling and stirring are continued until
the green vitriol has completely dissolved, when the greenish white
precipitate is allowed to settle, washed several times with water,
and then exposed to the air in thin layers. The precipitate, which
begins to turn yellow during washing, becomes in a short time ochre
yellow in the air, being changed into ferric hydroxide. After drying
and calcining, a fine red powder of pure ferric oxide is formed. The
shade depends on the temperature at which the substance is calcined:
the higher the temperature and the longer the heating is continued, the
darker is the product.
=Vogel’s Iron Red.=—This preparation, which is particularly brilliant
and therefore highly suitable for an artists’ colour, is made by
adding a saturated solution of oxalic acid to a boiling solution of
green vitriol. The greenish yellow precipitate of ferrous oxalate is
collected on a filter and well washed with water. After drying, the
precipitate is heated in a shallow iron dish to a temperature of 200°
C., at which the ferrous oxalate decomposes and is converted into a
soft fiery red powder consisting of pure ferric oxide. By igniting this
powder in covered crucibles the different shades of ferric oxide can be
obtained.
=Macay’s English Red.=—Seven hundred and four parts of ferrous
sulphate, 1,000 parts of copper chloride, and 1,678 parts of common
salt are dissolved, the solution boiled and the precipitate ignited.
In the manufacture of fuming or Nordhausen sulphuric acid, ferric oxide
is obtained as a residue. It is then known under the names of English
red, _caput mortuum_, colcothar, rouge and Indian red as a very cheap
pigment. It is also used as a polishing material. Fuming sulphuric acid
is made by heating green vitriol at a white heat in retorts placed
in furnaces; sulphur dioxide and trioxide are evolved, whilst in the
retorts there remains a residue of almost pure ferric oxide, containing
small quantities of basic ferric sulphate, which can only be decomposed
by long continued violent heating. The vapours of sulphur trioxide are
caught in receivers containing oil of vitriol, in which they dissolve
and produce fuming sulphuric acid.
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