The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The residue in the retorts, which has only a low commercial value,
can be converted into a good pigment without the expenditure of much
money or labour. It is ground in mills as finely as possible, and,
if necessary, afterwards levigated. The fine powder is mixed with
varying quantities of common salt, the object of which is to prevent
the temperature from rising too high in the calcining process. Common
salt is volatile at a temperature approaching a strong red heat; when
the temperature has once risen so far, a further rise is prevented by
the heat taken up in volatilising the salt. In order to make ferric
oxide of a yellow tinge, 2 per cent. of salt are added, and the mixture
heated with a moderate fire for 1 hour. To obtain the deeper shades,
the addition of common salt is increased even to 6 per cent. For a
brownish-red oxide, 4 per cent. of salt are added and the mixture
heated for 4 hours; for a dark violet oxide, 6 per cent. of salt are
used, and the mixture is heated for 6 hours with the fiercest fire.
It has been observed that the shade of the product is finer the more
completely air is excluded from the glowing mass and the more quickly
the product, after sufficient heating, is cooled down to the ordinary
temperature.
Fire-clay tubes are used for heating the ferric oxide, which are
similar to gas retorts, and are built one above the other in furnaces.
The number in one furnace may reach 60. Each retort is closed by a
well-fitting lid, which is luted with clay after the retorts are
filled, a small opening being left through which the heated air may
escape. If the retorts were closed completely air-tight they would
burst on heating.
Ferric oxide pigments are made in very large quantity by several works,
which bring up to 20 different shades, varying from reddish yellow to
dark violet, into the market.
On account of their great resistance to the action of the atmosphere
and of chemical agents, the ferric oxide pigments are particularly
suitable for painting iron and other metals which are exposed to air or
water. They are also suited to fresco work.
Lower qualities of iron reds are made by calcining ochres, large
deposits of which occur in nature, and also from the residues of basic
ferric sulphate obtained in the alum manufacture. These varieties
are at the best usable for ordinary painting, but never for artists’
pigments.
According to the method of Steinau, iron pigments can be made from
wrought-iron scraps, turnings, etc., by causing them to rust through
alternate contact with air and water. The resulting ferric hydrate is
either at once used as a pigment or converted into other shades by
calcining. By heating in the air a red pigment is formed; by heating
with coal in the absence of air a black; and from mixtures of red and
black different shades of brown. If the iron turnings can be obtained
cheap, this process should be well adapted to the manufacture of fine
iron pigments.
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