The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Many organic colouring matters, soluble in water, have the property
of forming compounds with metallic oxides, soluble with great
difficulty, when their solutions are mixed with a salt of lead, tin or
aluminium, and the oxide is separated from the solution by an alkali.
The precipitates obtained in this way are insoluble compounds of the
colouring matter and the oxide of the metal; they are called lake
pigments, or, briefly, lakes. A large number of pigments, often of
great beauty, is obtained in this manner. The lakes are widely used in
all branches of painting and dyeing.
Of great importance for the quality of the pigment is the physical
condition of the precipitate; this is either crystalline or amorphous,
that is, non-crystalline. When a crystalline precipitate is examined
under the microscope, it is seen to consist of very small, coloured,
transparent crystals. The amorphous precipitates are, however, in such
a fine state of division that even with the highest magnification
they transmit little or no light, and consequently appear opaque.
These different characters of precipitates have the greatest influence
on that property of pigments which we call _covering power_. In
consequence of its transparency, a crystalline precipitate will allow
the colour of the surface upon which it is spread to appear through,
hence it must be laid on much more thickly than is necessary with an
opaque pigment, of which a thin coating is sufficient to make the
colour of the surface beneath invisible.
How extremely important is the crystalline or non-crystalline nature
of a precipitate in practice is seen by a consideration of white lead.
This pigment, lead carbonate, can be made by mixing solutions of a
lead salt and a soluble carbonate (soda); but in this case a lead
carbonate of crystalline nature is formed, which, being transparent, is
of so small covering power that this process has no application in the
manufacture of white lead; but a far more troublesome method is used by
which a non-crystalline product, amorphous lead carbonate, is obtained.
Many pigments are formed by burning (oxidising) metals, as, for
example, zinc white; others are prepared by melting salts together, as
Naples yellow; others again are formed by very complicated processes
still partially unexplained, as is the case with ultramarine. In the
manufacture of colours we find all chemical processes in use.
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